Gattar中试厂尾渣堆除残铀的处理,埃及东部沙漠

A. RedaGazala, S. MohamedNagar
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引用次数: 2

摘要

东部沙漠Gattar铀矿化品位较低,含铀量约为300 ppm。2000年建立了浸出铀和生产商业黄饼的中试工厂。在浸出过程中产生了大量的残留物,铀含量约为85 ppm。本研究主要是从先前从gattar铀矿化中还原浸出的铀中已经存在的残留物中浸出铀。还原浸出是将矿化后的花岗岩粉碎,放入大桶中,再用适当浓度的硫酸溶液冲洗,以浸出铀的静态浸出过程。采用硫酸浸出-离子交换工艺流程,优化了浸出低酸浓度铀的工艺条件。最后用氢氧化钠沉淀回收铀。通过批量试验,考察了接触时间、磨矿粒度、L/S比和浸出剂浓度对残渣(尾矿)浸出铀的影响。为了验证铀浸出在大规模应用中的可行性,进行了铀柱浸出试验。结果表明,采用动态浸出法处理还原浸出渣是可行的。在酸用量为1.5%w/w的条件下,渣中铀的回收率约为83%,晶粒尺寸小于10 mm,总液固比为0.8 m3/t。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Processing of Gattar Pilot Plants Tailing Piles for Removing Residual Uranium, Eastern Desert, Egypt
Gattar uranium mineralization in eastern desert is of comparatively low grade containing about 300 ppm uranium. A pilot plant for leaching of uranium and produce commercial yellow cake was set up in 2000. A huge amount, of residues resulted during leaching process with uranium assay about 85 ppm uranium. The present study was performed mainly to leach of uranium from the already present residues resulted from previous uranium vat leaching from gattar uranium mineralization. Vat leaching, is a static process in which the mineralized granite is crushed, disposed in vats and irrigated with a sulfuric acid solution with proper concentration to leach the uranium. The flowsheet adopted is of sulfuric acid leach-ion exchange process, the leaching was optimized to leach uranium with low acid concentration. Uranium is finally recovered by precipitation with sodium hydroxide. The uranium leaching from the residues (tailings) were examined by re-crashed coarse size via a batch experiments as a function of contact time, grind size, L/S ratio and lixiviant concentration at ambient temperature. To verifying the feasibility of uranium leaching in large-scale applications, column leaching of uranium was carried out. The results indicate the feasibility of treating the residue of the vat leaching through dynamic leaching. recovery of about 83% of uranium in the residue was obtained using a 1.5%w/w consumption of acid, grain size is ˂10 mm and total liquidsolid ratio is 0.8 m3/t.
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