含4,4′-二羟基二苯甲酮阻燃型聚苯基膦酸盐的制备与纯化

IF 1 Q4 CHEMISTRY, MULTIDISCIPLINARY

Chemistry & Chemical Technology Pub Date : 2022-02-20 DOI:10.23939/chcht16.01.095

G. Possenti, A. De Souza, R. Battisti, Juliani Conti Martins Dominguini, L. Dominguini, C. Soares, H. Riella

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引用次数: 0

摘要

合成了一种含4,4′-二羟基苯甲酮的聚苯基膦酸盐作为阻燃剂。然而，杂质被检测到，并可能损害其性能和热稳定性。因此，提出了一种以水和己烷回流萃取为基础的纯化路线。结果表明，在不破坏聚合物的情况下，成功地去除杂质，特别是P-Cl基团。

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Preparation and Purification of a Flame-Retardant Polyphenylphosphonate Containing 4,4'-Dihydroxybenzophenone

A polyphenylphosphonate containing 4,4'-dihydroxybenzophenone was synthesized as a flame retardant. However, impurities were detected and may compromise its properties and thermal stability. Thus, a purification route based on water and hexane extraction with reflux was proposed. Results showed success in removing impurities, especially P–Cl groups, without damaging the polymer.

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来源期刊

Chemistry & Chemical Technology CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

1.70

自引率

44.40%

发文量