{"title":"振荡反应条件对整体式汽车催化转化器中三氧化硫生成的抑制作用","authors":"P. Olsson, N. Schoeoen","doi":"10.1021/I200033A031","DOIUrl":null,"url":null,"abstract":"The net formation of sulfur trioxide in the presence of an excess of carbon monoxide with respect to sulfur dioxide was studied under different reaction conditions in a single element of a commercial monolithic Pt, Rh converter. Conditions giving rise to self-oscillations were found to result in a complete oxidation of carbon monoxide and in only a 10% net conversion of sulfur dioxide.","PeriodicalId":13537,"journal":{"name":"Industrial & Engineering Chemistry Process Design and Development","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1986-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Suppression of sulfur trioxide formation in a monolithic catalytic converter for cars due to oscillating reaction conditions\",\"authors\":\"P. Olsson, N. Schoeoen\",\"doi\":\"10.1021/I200033A031\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The net formation of sulfur trioxide in the presence of an excess of carbon monoxide with respect to sulfur dioxide was studied under different reaction conditions in a single element of a commercial monolithic Pt, Rh converter. Conditions giving rise to self-oscillations were found to result in a complete oxidation of carbon monoxide and in only a 10% net conversion of sulfur dioxide.\",\"PeriodicalId\":13537,\"journal\":{\"name\":\"Industrial & Engineering Chemistry Process Design and Development\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1986-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Industrial & Engineering Chemistry Process Design and Development\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1021/I200033A031\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Industrial & Engineering Chemistry Process Design and Development","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1021/I200033A031","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Suppression of sulfur trioxide formation in a monolithic catalytic converter for cars due to oscillating reaction conditions
The net formation of sulfur trioxide in the presence of an excess of carbon monoxide with respect to sulfur dioxide was studied under different reaction conditions in a single element of a commercial monolithic Pt, Rh converter. Conditions giving rise to self-oscillations were found to result in a complete oxidation of carbon monoxide and in only a 10% net conversion of sulfur dioxide.
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