水泥成分对高温条件下钢筋混凝土结构性能的影响

O. Bashynskyi, M. Peleshko, S. Vovk, O. Pazen
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摘要

本文研究了加热至1000℃对混凝土粘结剂硬化过程的影响及水泥相组成的变化С。在水泥复合材料中,活性矿物添加剂的存在增加了混凝土在常温下以及在火中加热时的强度。结构的破坏,伴随着混凝土在火灾高温的影响下强度特性的丧失,这是由于含水的结晶水合物的分解,这些水合物是在与水锁住时形成的。对波特兰水泥与草甸废物应用的物理和力学研究结果的分析表明,由于形成额外数量的硫酸钠或钾,它们的载荷允许显著增加这种水泥石的强度。它们作为硬化活化剂的影响在初始阶段最为显著,随着硬化时间的延长而逐渐减弱。研究表明,在草甸基添加剂和水硅酸盐的粘结剂组成中使用,可以使水泥石的强度提高1.5倍,这对于在高温工作的基础上开发有效的复合粘结剂是必不可少的。其中,氟化铝在硅油中的存在量(重量比为3.3%)决定了其对水泥的塑化效果。实验表明,在500℃以上的混凝土加热过程中,水泥石水化组分的破坏伴随着单个颗粒之间结构键的破坏,强度特性显著降低。在这种情况下,应用程序的使用在加热期间的固相反应过程中提供了CaO的部分耦合。事实证明,使用复合水泥作为粘合剂,由于其草甸应用成分的存在-加速硬化并改善强度特性,硅油-在高达1000°С的压力下将残余强度提高2.4 MPa。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
INFLUENCE OF THE CEMENT COMPOSITION ON THE PROPERTIES OF REINFORCED CONCRETE STRUCTURES WORKING IN HIGH TEMPERATURE CONDITIONS
In the article the influence of binder hardening of concrete processes and changes in the phase composition of cement by heating to 1000 °С. It was established that the presence of active mineral adds in cement composite increases the strength of concrete at ordinary temperatures as well as when heated in a fire.  Damage of structures, accompanied by loss of strength characteristics of concrete under the influence of high temperatures of the fire due to the decomposition of water-containing crystalline hydrates, which are formed when locked up with water. The analysis of the results of physical and mechanical investigations of portland cement with applications of meadow waste has shown that their loading allows to significantly increase the strength of this cement stone, due to the formation of an additional amount of sodium sulfate or potassium. Their influence as activators of hardening is most noticeable in the initial terms and gradually decreases with age of hardening. It has been shown that use in the composition of the binder of meadow-based additives and hydrosilics makes it possible to increase the strength of the cement stone by 1.5 times, which is essential for the development of effective composite binders on its basis for work in high temperatures. In this, the presence of fluoride aluminium in hydrosilic in a quantity of 3.3% by weight determines its plastisizing effect on cement. It has been experimentally stated that during the heating of concrete above 500°C, the destruction of hydrated components of cement stone with the destruction of structural bonds between individual particles with a significant decrease in strength characteristics. In this case, the use of applications provides a partial coupling of CaO in the process of solid phase reactions during heating. It is proved that the use of composite cement, as a binder, due to the presence of its composition of a meadow-based application - accelerates hardening and improves strength characteristics, hydrosilics - increases residual strength at a pressure of up to 1000°С by 2.4 MPa .
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