乙醇与汽车混合汽油影响的实验研究

Aboul Fotouh Tm, O. A. Mazen, I. Ashour
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引用次数: 6

摘要

这项工作的目的是调查生产的可能性高辛烷值环保乙醇汽油混合物的基础上的欧洲规格。环保型汽油是保证环境安全和清洁的关键要素。此外,它减少了汽油燃烧后的气体排放。生产环保型汽油的主要方法之一是将汽油与含氧化合物(如乙醇)混合。与其他含氧化合物相比,乙醇对汽油的物理化学特性影响较大,因此在其他含氧化合物中选择了乙醇。此外,它具有高辛烷值以及不污染环境和清洁添加剂。在实验研究中,环保型汽油的选择是基于欧- 3规范和欧-5规范对无乙醇混合的样品和有乙醇混合的样品;后升级。制备了重整油、异构油、全精油、重直馏油、加氢裂化油、重加氢裂化油、焦化油和重焦化油等不同类型的混合油。在本研究中,采用ASTM标准方法对火花点火燃料进行物理和化学特性表征。结果表明,得到了最佳规格的铕-3,其理化性能为:密度为755.11 Kg/m3, API为55.88,RON为95,MON为88,芳香族含量为40%,苯含量为0.66%。此外,ASTM蒸馏曲线显示,在150°C时的体积百分比为83。同时,终沸点(FBP)和回收率分别为198℃和96%。而另一种样品具有最差的物理和化学性质,因此它与乙醇混合以提高其特性。因此,目标是确定最佳乙醇体积百分比,以混合最差的样品,以产生最高性能的汽油。这些共混物分别为E0、E5、E10、E15、E20。结果表明,改造后的E5为欧5规格的最佳原料,其理化性能为745.55 Kg/m3, oAPI为58 Kg/m3, RON为101 Kg/m3, MON为98 Kg/m3,芳香烃体积含量为32.65%,苯体积含量为0.47%。此外,ASTM蒸馏曲线表明,在150°C时的体积百分比为75。同时,终沸点(FBP)为190℃,回收率为97%。其Reid蒸气压为8.1 psi,燃烧热为35 MJ/L。最后,将汽油与乙醇混合是环保汽油生产的关键问题。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
An Experimental Study on the Influence of Ethanol and Automotive GasolineBlends
The objective of this work is to investigate the production possibility of high octane environmental ethanol gasoline blends based on Euro specifications. The environmental gasoline is the key element to keep the environment safe and clean. Moreover, it reduces gas emissions after combustion of gasoline. One of the main methods to produce the environmental gasoline is blending gasoline with oxygenated compounds such as ethanol. Ethanol is chosen among other oxygenated compounds as it has a high influence on physico-chemical characteristics of gasoline rather than other oxygenated compounds. In addition, it has a high octane number as well as it is not polluting the environment and clean additive. In the experimental study, the choice of environmental gasolines are based on Euro- 3 specifications for samples without ethanol blend and Euro-5 specifications for samples with ethanol blend; after upgrading. Various blend stocks have been prepared which have reformate, isomerate, full refinery naphtha (FRN), heavy straight run naphtha (HSRN), hydrocracked naphtha, heavy hydrocracked naphtha, coker naphtha and heavy coker naphtha. In this study, ASTM standard methods are performed for spark ignition fuels to characterize its physical and chemical properties. The results show that one has exhibited the optimum specifications of Euro-3 and thus its physico-chemical characteristics are 755.11 Kg/m3 of density, 55.88 of °API and 95 of RON, 88 of MON, 40% by volume of aromatic content and 0.66% by volume of benzene content. Moreover, ASTM distillation curve shows that the volume percentage at 150°C is 83. At the same time, the final boiling point (FBP) and recovery volume percent are 198°C is 96% respectively. While another sample has the poorest physical as well as chemical properties so that it is blended with ethanol to upgrade its characteristics. Therefore, the target is determining the optimum ethanol volume percent to be blended with poorest sample to yield the highest properties of gasoline. These blends are namely as E0, E5, E10, E15, E20. The results indicate that E5 is the optimum one for Euro-5 specifications after upgrading and thus its physico-chemical characteristics are 745.55 Kg/m3 of density, 58 of oAPI, 101 of RON, 98 of MON, 32.65% by volume of aromatic content and 0.47% by volume of benzene content. Moreover, ASTM distillation curve illustrates that the volume percentage at 150°C is 75. At the same time, the final boiling point (FBP) and recovery volume percent are 190°C and 97% respectively. In addition, its Reid vapor pressure equals 8.1 psi and the heat of combustion equals 35 MJ/L. In the final, Blending gasoline with ethanol is an essential issue concerning the production of environmental gasolines.
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