导论章:陶瓷材料-合成、表征、应用和回收

D. Eliche-Quesada, L. Pérez-Villarejo, P. Sánchez-Soto
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引用次数: 1

摘要

陶瓷材料可以定义为由金属和非金属元素组合而成的无机材料,其性质取决于这些元素的连接方式[1,2]。陶瓷材料是材料中用途最广的一个分支。这种多功能性的起源在于其化学键的化学性质,因为它们主要由不同比例的强离子键和共价键组成。这些键决定了陶瓷材料的一系列特殊性能,其中包括较高的熔合温度、高模量、高耐磨强度、较差的热性能、高硬度和脆性结合韧性以及低延展性。除了由于它们结合形成化学键而缺乏传导电子之外,它们还是很好的电绝缘体。陶瓷材料可分为两大类:传统陶瓷和技术或高级陶瓷。传统陶瓷可以定义为以硅酸盐为基础的陶瓷,其中包括水泥、粘土制品和耐火材料。传统陶瓷产量大,是一个重要的市场。传统的陶瓷材料是用天然沉积物中的原料制成的,比如粘土材料。第二种是技术陶瓷或高级陶瓷,是用经过重要化学处理的人工原料制造的,以达到高纯度并改善其物理特性。因此,它们是用更先进和复杂的方法制造的。其中包括碳化物、氮化物、硼化物、纯氧化物,以及各种具有磁性、铁电、压电和超导等用途的陶瓷。这些陶瓷在极端拉伸条件下具有优异的机械性能,高耐磨强度或优异的电、磁或光学性能,或在高温和腐蚀环境下具有优异的强度,具有很高的抗化学侵蚀强度[3]。第三类是玻璃,虽然被认为是陶瓷,但要分开研究,因为它们与第一种玻璃陶瓷的晶体结构顺序不同。上述多功能性还允许陶瓷用于建筑和建筑行业的大量最终用户和应用,如粘土砖和砌块,卫生洁具以及墙地砖;在家庭
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Introductory Chapter: Ceramic Materials - Synthesis, Characterization, Applications and Recycling
Ceramic materials can be defined as inorganic materials constituted by the combination of metallic and nonmetallic elements whose properties depend on the way in which these elements are linked [1, 2]. Ceramic materials are the most versatile branch of materials. The origin of this versatility lies in the chemical nature of its bonds, since they are mainly constituted by strong ionic and covalent bonds in different proportions. The bonds determine a series of particular properties of ceramic materials among which are relatively high fusion temperatures, high modulus, high wear strength, poor thermal properties, high hardness and fragilities combined with tenacities, and low ductility. In addition to the lack of conduction electrons since they are combined forming chemical bonds, they are good electrical insulators. Ceramic materials can be divided into two large groups: traditional ceramics and technical or advanced ceramics. Traditional ceramics can be defined as those that are based on silicates, among which are cement, clay products, and refractories. Traditional ceramics are produced in large volumes and constitute an important market. Traditional ceramic materials are made with raw materials from natural deposits such as clay materials. The second group, technical or advanced ceramics, is manufactured with artificial raw materials that have undergone an important chemical processing to achieve a high purity and an improvement of their physical characteristics. Therefore, they are manufactured with more advanced and sophisticated methods. Among them are carbides, nitrides, borides, pure oxides, and a great variety of ceramics with magnetic, ferroelectric, piezoelectric, and superconducting applications, among others. These ceramics possess excellent mechanical properties under extreme conditions of tension, high wear strength or excellent electrical, magnetic, or optical properties, or exceptional strength to high temperatures and corrosive environments, showing high strength to chemical attack [3]. There is a third group that is glasses that, although considered ceramic, are studied separately because they differ from the first group in the order reached by their crystalline structures as glass-ceramics. The versatility mentioned above also allows ceramics to be used for a large number of end user and applications for the construction and building industry such as clay bricks and blocks, sanitary ware, and wall and floor tiles; in household
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