{"title":"环己-1-烯基和环己-1,4-二烯基甲胺的制备与脱胺","authors":"K. Stapleford","doi":"10.1039/J39710002580","DOIUrl":null,"url":null,"abstract":"The rearranged alcohol from the deamination of cyclohex-1-enylmethylamine is 2-methylenecyclohexanol, the product of an allylic rearrangement, and not the ring-expanded alcohol previously reported. An analogous reaction has been shown to take place with cyclohexa-1,4-dienylmethylamine.","PeriodicalId":17245,"journal":{"name":"Journal of The Chemical Society C: Organic","volume":"36 1","pages":"2580-2582"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Preparation and deamination of cyclohex-1-enyl- and cyclohexa-1,4-dienyl-methylamine\",\"authors\":\"K. Stapleford\",\"doi\":\"10.1039/J39710002580\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The rearranged alcohol from the deamination of cyclohex-1-enylmethylamine is 2-methylenecyclohexanol, the product of an allylic rearrangement, and not the ring-expanded alcohol previously reported. An analogous reaction has been shown to take place with cyclohexa-1,4-dienylmethylamine.\",\"PeriodicalId\":17245,\"journal\":{\"name\":\"Journal of The Chemical Society C: Organic\",\"volume\":\"36 1\",\"pages\":\"2580-2582\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society C: Organic\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J39710002580\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society C: Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J39710002580","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Preparation and deamination of cyclohex-1-enyl- and cyclohexa-1,4-dienyl-methylamine
The rearranged alcohol from the deamination of cyclohex-1-enylmethylamine is 2-methylenecyclohexanol, the product of an allylic rearrangement, and not the ring-expanded alcohol previously reported. An analogous reaction has been shown to take place with cyclohexa-1,4-dienylmethylamine.