用于选择性共轭加成反应的内向Brønsted酸性空腔体

IF 2.1 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Supramolecular Chemistry Pub Date : 2021-06-03 DOI:10.1080/10610278.2021.1981323

Y. Matsumoto, Y. Taguchi, Naruhiro Yoshida, Shugo Tokai, T. Maruyama, T. Iwasawa

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引用次数: 1

摘要

摘要:成功合成了四个新的具有磷酸氢二酯基团的喹诺啉跨空腔体。这些磷衍生物应用于Brønsted酸辅助催化共轭加成反应。结果与磷酸二苯氢对照及上述四种空腔体并列。构效关系表明，催化剂中心被两个错位的喹诺啉所包围，对反应谱和产物分布有显著影响。这一比较研究为今后的催化空腔化学和人工酶催化提供了理论基础。

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Introverted Brønsted acid cavitands for selective conjugate addition reactions

ABSTRACT Four new quinoxaline-spanned cavitands having a diester hydrogen phosphate group were successfully synthesised. These phosphorous derivatives were applied in Brønsted acid-assisted catalytic conjugate addition reactions. The results were ranked with the control of diphenyl hydrogen phosphate as well as among those four cavitands. The structure–activity relationship revealed that the catalyst centre surrounded by two trans-positioned quinoxalines significantly influences reaction profile and product distribution. This comparative study provides us an intellectual basis for future catalytic cavitand chemistry and artificial enzymatic catalysis.

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来源期刊

Supramolecular Chemistry 化学-化学综合

CiteScore

3.60

自引率

3.00%

发文量

审稿时长

2.7 months

期刊介绍： Supramolecular Chemistry welcomes manuscripts from the fields and sub-disciplines related to supramolecular chemistry and non-covalent interactions. From host-guest chemistry, self-assembly and systems chemistry, through materials chemistry and biochemical systems, we interpret supramolecular chemistry in the broadest possible sense. Interdisciplinary manuscripts are particularly encouraged. Manuscript types include: high priority communications; full papers; reviews, and; Methods papers, techniques tutorials highlighting procedures and technologies that are important to the field. We aim to publish papers in a timely fashion and as soon as a paper has been accepted and typeset it will be published in electronic form on the Latest articles section of the website. The two most important review criteria are that the paper presents high-quality work that fits generally into the broad spectrum of activities in the supramolecular chemistry field. Under normal circumstances, Supramolecular Chemistry does not consider manuscripts that would be more suitable in a highly specialized journal. This includes, but is not limited to, those based mostly or exclusively on topics such as solid state/X-ray structures, computational chemistry, or electrochemistry. . The two most important review criteria are that the paper presents high-quality work that fits generally into the broad spectrum of activities in the supramolecular chemistry field.