塑料废弃物在实际情况下的热解模拟

Zijian Wang
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引用次数: 0

摘要

如今,由于生产条件和制造工艺的不同,同一类型塑料制品的物理和化学品质会有很大差异,这使得废旧塑料制品难以分类,增加了回收利用的难度。本文介绍了三种热塑性塑料:聚丙烯(PP);聚苯乙烯(PS);和高密度聚乙烯(HDPE),利用热重分析法(TGA)检测和分析废塑料的热解性能,并计算热塑性塑料在热解反应中的动力学参数。研究发现,塑料的混合热解有利于热解反应,但随着更稳定的HDPE含量的增加,反应所需的活化能也随之增加。通过模拟废塑料的实际比例,并对其进行热解,确定了最佳热解温度范围和热解活化能。研究结果将对大规模废塑料热解的工程发展起到预测和指导作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Pyrolysis Simulation of Plastic Wastes in Actual Situation
Nowadays, the physical and chemical qualities of the same type of plastic goods can vary significantly due to production conditions and manufacturing processes, making it difficult to categorize discarded plastic products and increasing the difficulty of recycling. In this paper, three thermoplastics: polypropylene (PP); polystyrene (PS); and high-density polyethylene (HDPE), are used to detect and analyze the pyrolysis properties of waste plastics using Thermogravimetric Analysis (TGA) and to calculate the kinetic parameters of thermoplastics in the pyrolysis reaction. It is found that the mixed pyrolysis of plastics facilitates the pyrolysis reaction, but the required activation energy of the reaction increases if the content of more stable HDPE gains. The optimum pyrolysis temperature range and activation energy of pyrolysis are discovered by modelling the real proportion of waste plastics and pyrolyzing them. And the results will predict and guide the engineering development for mass waste plastic pyrolysis.
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