三(羟甲基)氨基甲烷盐酸盐在20% (v/v)丙酮-水体系中的输运性质研究

A. Dixit
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引用次数: 0

摘要

在20% (v/v)丙酮-水体系303.15°K中测定了Tris-(羟甲基)氨基甲烷盐酸盐的粘度。相关参数为粘度()的实验值,可分别确定相对粘度()、Jones-Dole方程的粘度系数、黏性流动激活自由能、每摩尔溶剂自由能和溶质自由能。计算了Grunberg和Nissan的超摩尔体积、超粘度、超吉布自由能和相互作用参数。这些研究对表征溶液的结构和性质有很大的帮助。在水中加入有机溶剂会使离子的溶剂化发生急剧变化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study of Transport Properties of Tris (hydroxymethyl)aminomethane Hydrochloride in 20% (v/v) Acetone-Water System at
Viscometric properties of Tris-(hydroxymethyl)amino methane hydrochloride are measured in 20% (v/v) acetone-water system 303.15°K. The related parameters are the experimental values of viscosity () allow to determine relative viscosity (), viscosity -coefficient of the Jones-Dole equation, free energies of activation of viscous flow and per mole solvent, and solute, respectively. The excess molar volume, excess viscosity, excess Gibb’s free energy, and interaction parameter of Grunberg and Nissan have also been calculated. These studies are of great help in characterizing the structure and properties of solutions. The addition of an organic solvent to water brings about a sharp change in the solvation of ions.
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