甾烷系列22-和23-去羟基油菜素内酯的合成

Q4 Chemistry

Proceedings of the National Academy of Sciences of Belarus, Chemical Series Pub Date : 2023-09-04 DOI:10.29235/1561-8331-2023-59-3-202-210

V. Khripach, V. Zhabinskii, E. V. Sikorov, S. I. Lazarev

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引用次数: 0

摘要

已经进行了先前描述的异卡斯特酮的22-和23-脱氧类似物的合成，这使得无需替换侧链的碳骨架即可获得目标化合物。合成过程中的关键反应是环氧环开环和自由基脱溴。

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Synthesis of 22- and 23-dehydroxybrassinosteroids of the stigmastane series

The synthesis of previously undescribed 22- and 23-deoxyanalogues of homocastasterone has been carried out, which makes it possible to obtain target compounds without replacing the carbon skeleton of the side chain. The key reactions in their synthesis were epoxy ring opening and radical debromination.

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来源期刊

Proceedings of the National Academy of Sciences of Belarus, Chemical Series Chemistry-Chemistry (miscellaneous)

CiteScore

0.30

自引率

0.00%

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