可持续香草素修饰的玻璃体:合成、挑战与展望

Reactions Pub Date : 2023-01-02 DOI:10.3390/reactions4010003
M. A. Rashid, Md Nabiul Hasan, MD Anisur Rahman Dayan, Mohammad Salman Ibna Jamal, M. K. Patoary
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引用次数: 9

摘要

近90%的热固性塑料是由石油资源生产的,它们具有显著的机械特性、化学耐久性和尺寸稳定性。然而,在生产、使用和处置过程中,它们会导致全球变暖、石油储备枯竭和环境污染。利用可再生资源形成热固性材料是解决上述问题的最关键方面之一。香兰素基原料因其结构易于修饰而被广泛应用于高分子材料的工业制造中。相反,传统热固性材料作为一类广泛的高分子量分子,由于其永久的3-D交联网络,其愈合、分解和恢复具有挑战性。一旦产品损坏,回收问题就会出现,造成资源损失和环境影响。这可以通过在聚合物链中插入动态共价自适应网络(dcan)来解决,从而延长产品寿命,并最大限度地减少浪费。这也提高了这些产品在前景领域的吸引力。此外,必须强调的是,增加产品寿命和减少浪费相当于减少消耗资源的费用。详细的合成,再加工,热学和力学特性的部分和全部生物质热固性聚合物由香草素改性单体涵盖在目前的工作。最后,综述强调了这些新兴的香草素修饰的玻璃体作为传统不可回收热固性材料的潜在替代品的好处、困难和应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A Critical Review of Sustainable Vanillin-modified Vitrimers: Synthesis, Challenge and Prospects
Nearly 90% of thermosets are produced from petroleum resources, they have remarkable mechanical characteristics, are chemically durable, and dimensionally stable. However, they can contribute to global warming, depletion of petroleum reserves, and environmental contamination during manufacture, use, and disposal. Using renewable resources to form thermosetting materials is one of the most crucial aspects of addressing the aforementioned issues. Vanillin-based raw materials have been used in the industrial manufacturing of polymer materials because they are simple to modify structurally. Conversely, traditional thermosetting materials as a broad class of high-molecular-weight molecules are challenging to heal, decompose and recover owing to their permanent 3-D crosslinking network. Once the products are damaged, recycling issues could arise, causing resource loss and environmental impact. It could be solved by inserting dynamic covalent adaptable networks (DCANs) into the polymer chains, increasing product longevity, and minimizing waste. It also improves the attractiveness of these products in the prospective field. Moreover, it is essential to underline that increasing product lifespan and reducing waste is equivalent to reducing the expense of consuming resources. The detailed synthesis, reprocessing, thermal, and mechanical characteristics of partly and entirely biomass thermosetting polymers made from vanillin-modified monomers are covered in the current work. Finally, the review highlights the benefits, difficulties, and application of these emerging vanillin-modified vitrimers as a potential replacement for conventional non-recyclable thermosets.
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