在HF存在下,一种新型醋酸结构微孔磷酸铝的合成与表征

Guangshan Zhu , Feng-Shou Xiao , Shilun Qiu , Pang-Cho Hun , Ruren Xu , Shujie Ma , Osamu Terasaki
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引用次数: 18

摘要

以氢氧托品为有机模板剂,在HF存在下成功合成了具有列文结构的磷酸铝类似物(AlPO4-35)的微孔晶体。一般在Al2O3:P2O5:1.5 Tropine:HF: 200h2o的起始组成下,结晶产物为微孔材料AlPO4-5;虽然起始组成相同,但在100℃下预处理10 h可生成具有莱文结构的磷酸铝类似物(AlPO4-35)。通过x射线粉末衍射观察在100℃下的预处理结果表明,AlPO4·2H2O(变瓦石/张纹石)的结晶度较差,在微孔AlPO4-35的合成中起着重要的反应中间体作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and characterization of a new microporous aluminophosphate with levyne structure in the presence of HF

Microporous crystal of the aluminophosphate analogue with levyne structure (AlPO4-35) were successfully synthesized in the presence of HF using tropine hydroxide as an organic template. Generally, under a starting composition of Al2O3:P2O5:1.5 Tropine:HF:200 H2O, the crystallization product is the microporous material AlPO4-5; a pretreatment at 100 °C for 10 h leads to the formation of the aluminophosphate analogue with levyne structure (AlPO4-35), although the starting composition is the same. Observation of the pretreatment at 100 °C by X-ray powder diffraction showed that poorly crystalline AlPO4 · 2H2O (metavariscite/variscite) plays an important role as reactive intermediate in the synthesis of microporous AlPO4-35.

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