Guangshan Zhu , Feng-Shou Xiao , Shilun Qiu , Pang-Cho Hun , Ruren Xu , Shujie Ma , Osamu Terasaki
{"title":"在HF存在下,一种新型醋酸结构微孔磷酸铝的合成与表征","authors":"Guangshan Zhu , Feng-Shou Xiao , Shilun Qiu , Pang-Cho Hun , Ruren Xu , Shujie Ma , Osamu Terasaki","doi":"10.1016/S0927-6513(97)00045-X","DOIUrl":null,"url":null,"abstract":"<div><p>Microporous crystal of the aluminophosphate analogue with levyne structure (AlPO<sub>4</sub>-35) were successfully synthesized in the presence of HF using tropine hydroxide as an organic template. Generally, under a starting composition of Al<sub>2</sub>O<sub>3</sub>:P<sub>2</sub>O<sub>5</sub>:1.5 Tropine:HF:200 H<sub>2</sub>O, the crystallization product is the microporous material AlPO<sub>4</sub>-5; a pretreatment at 100 °C for 10 h leads to the formation of the aluminophosphate analogue with levyne structure (AlPO<sub>4</sub>-35), although the starting composition is the same. Observation of the pretreatment at 100 °C by X-ray powder diffraction showed that poorly crystalline AlPO<sub>4</sub> · 2H<sub>2</sub>O (metavariscite/variscite) plays an important role as reactive intermediate in the synthesis of microporous AlPO<sub>4</sub>-35.</p></div>","PeriodicalId":100926,"journal":{"name":"Microporous Materials","volume":"11 5","pages":"Pages 269-273"},"PeriodicalIF":0.0000,"publicationDate":"1997-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0927-6513(97)00045-X","citationCount":"18","resultStr":"{\"title\":\"Synthesis and characterization of a new microporous aluminophosphate with levyne structure in the presence of HF\",\"authors\":\"Guangshan Zhu , Feng-Shou Xiao , Shilun Qiu , Pang-Cho Hun , Ruren Xu , Shujie Ma , Osamu Terasaki\",\"doi\":\"10.1016/S0927-6513(97)00045-X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Microporous crystal of the aluminophosphate analogue with levyne structure (AlPO<sub>4</sub>-35) were successfully synthesized in the presence of HF using tropine hydroxide as an organic template. Generally, under a starting composition of Al<sub>2</sub>O<sub>3</sub>:P<sub>2</sub>O<sub>5</sub>:1.5 Tropine:HF:200 H<sub>2</sub>O, the crystallization product is the microporous material AlPO<sub>4</sub>-5; a pretreatment at 100 °C for 10 h leads to the formation of the aluminophosphate analogue with levyne structure (AlPO<sub>4</sub>-35), although the starting composition is the same. Observation of the pretreatment at 100 °C by X-ray powder diffraction showed that poorly crystalline AlPO<sub>4</sub> · 2H<sub>2</sub>O (metavariscite/variscite) plays an important role as reactive intermediate in the synthesis of microporous AlPO<sub>4</sub>-35.</p></div>\",\"PeriodicalId\":100926,\"journal\":{\"name\":\"Microporous Materials\",\"volume\":\"11 5\",\"pages\":\"Pages 269-273\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1997-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0927-6513(97)00045-X\",\"citationCount\":\"18\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Microporous Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S092765139700045X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Microporous Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S092765139700045X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and characterization of a new microporous aluminophosphate with levyne structure in the presence of HF
Microporous crystal of the aluminophosphate analogue with levyne structure (AlPO4-35) were successfully synthesized in the presence of HF using tropine hydroxide as an organic template. Generally, under a starting composition of Al2O3:P2O5:1.5 Tropine:HF:200 H2O, the crystallization product is the microporous material AlPO4-5; a pretreatment at 100 °C for 10 h leads to the formation of the aluminophosphate analogue with levyne structure (AlPO4-35), although the starting composition is the same. Observation of the pretreatment at 100 °C by X-ray powder diffraction showed that poorly crystalline AlPO4 · 2H2O (metavariscite/variscite) plays an important role as reactive intermediate in the synthesis of microporous AlPO4-35.