裂纹核模型在磁铁矿还原为浮士体中的应用

J. Janowski, A. Barański, M. Łagan, J. Nedoma, A. Sadowski
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引用次数: 3

摘要

用热重法研究了磁铁矿在1293 K下还原为浮士体Fe0.936O的过程。在接近大气压的条件下,用CO2 + CO混合气体对半径在0.3 ~ 5.0 mm范围内的球状样品进行还原。得到了s型动力学曲线。1975年Park和Levenspiel提出的噼啪核心模型与数据吻合。该模型考虑了固体颗粒的脆裂和化学反应。详细讨论了模型的适用范围,并对原有的参数计算方法作了一定的修改。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
On the application of the crackling core model to the reduction of magnetite to wustite

The reduction of magnetite to wustite Fe0.936O was studied by means of thermogravimetry at 1293 K. Sphere-like samples of constant radius, within the radius range 0.3–5.0 mm, were reduced by flowing a CO2 + CO gas mixture at nearly atmospheric pressure. Sigmoidal-type kinetic curves were obtained.

The crackling core model proposed in 1975 by Park and Levenspiel fits the data. The model takes into account crackling of solid grains and a chemical reaction. The limits of applicability of the model are discussed in more detail and the original procedure for calculating its parameters was modified to some extent.

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