{"title":"聚苯胺/硅胶复合材料对铅(II)的吸附:动力学和等温线研究","authors":"Mas Inda Putrinesia, N. Nurlina, W. Rahmalia","doi":"10.26418/INDONESIAN.V1I3.34196","DOIUrl":null,"url":null,"abstract":"Research on the study of kinetics and isotherm adsorption of Pb(II) by polyaniline/silica gel (PANI/SiO2) composite from glass waste has successfully been done. The polymerization of silica gel was prepared by sol-gel process. Meanwhile, PANI/SiO2 composite was prepared using sulfuric acid (H2SO4) as its dopants and hydrogen peroxide (H2O2) for oxidation process. Composition of oxide compound in PANI/SiO2 composite was analyzed by X-Ray Fluorosence (XRF) and Gas Sorption Analyzer (GSA). Adsorption of Pb(II) was carried out by contacting PANI/SiO2 with Pb(NO3)2 solution for 20, 40, 60 and 80 minutes, with concentrations of 150, 200, 250, 300, 350 and 400 mg/L. The optimum contact time was reached at 40 minutes. This adsorption followed pseudo-second order model with R2= 0.996. The first optimum adsorption capacity was reached in the concentration of 250 mg/L. Isotherm adsorption followed Langmuir models with R2= 0.954 (monolayer capacity= 51.02 mg/g).","PeriodicalId":13554,"journal":{"name":"Indonesian Journal of Pure and Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2019-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"ADSORPTION OF Pb(II) BY POLYANILINE/SILICA GEL COMPOSITE: KINETICS AND ISOTHERM STUDIES\",\"authors\":\"Mas Inda Putrinesia, N. Nurlina, W. Rahmalia\",\"doi\":\"10.26418/INDONESIAN.V1I3.34196\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Research on the study of kinetics and isotherm adsorption of Pb(II) by polyaniline/silica gel (PANI/SiO2) composite from glass waste has successfully been done. The polymerization of silica gel was prepared by sol-gel process. Meanwhile, PANI/SiO2 composite was prepared using sulfuric acid (H2SO4) as its dopants and hydrogen peroxide (H2O2) for oxidation process. Composition of oxide compound in PANI/SiO2 composite was analyzed by X-Ray Fluorosence (XRF) and Gas Sorption Analyzer (GSA). Adsorption of Pb(II) was carried out by contacting PANI/SiO2 with Pb(NO3)2 solution for 20, 40, 60 and 80 minutes, with concentrations of 150, 200, 250, 300, 350 and 400 mg/L. The optimum contact time was reached at 40 minutes. This adsorption followed pseudo-second order model with R2= 0.996. The first optimum adsorption capacity was reached in the concentration of 250 mg/L. Isotherm adsorption followed Langmuir models with R2= 0.954 (monolayer capacity= 51.02 mg/g).\",\"PeriodicalId\":13554,\"journal\":{\"name\":\"Indonesian Journal of Pure and Applied Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-07-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Indonesian Journal of Pure and Applied Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.26418/INDONESIAN.V1I3.34196\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Indonesian Journal of Pure and Applied Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.26418/INDONESIAN.V1I3.34196","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
ADSORPTION OF Pb(II) BY POLYANILINE/SILICA GEL COMPOSITE: KINETICS AND ISOTHERM STUDIES
Research on the study of kinetics and isotherm adsorption of Pb(II) by polyaniline/silica gel (PANI/SiO2) composite from glass waste has successfully been done. The polymerization of silica gel was prepared by sol-gel process. Meanwhile, PANI/SiO2 composite was prepared using sulfuric acid (H2SO4) as its dopants and hydrogen peroxide (H2O2) for oxidation process. Composition of oxide compound in PANI/SiO2 composite was analyzed by X-Ray Fluorosence (XRF) and Gas Sorption Analyzer (GSA). Adsorption of Pb(II) was carried out by contacting PANI/SiO2 with Pb(NO3)2 solution for 20, 40, 60 and 80 minutes, with concentrations of 150, 200, 250, 300, 350 and 400 mg/L. The optimum contact time was reached at 40 minutes. This adsorption followed pseudo-second order model with R2= 0.996. The first optimum adsorption capacity was reached in the concentration of 250 mg/L. Isotherm adsorption followed Langmuir models with R2= 0.954 (monolayer capacity= 51.02 mg/g).