液体中掺Nd3+ α-NaYF4纳米晶体的局部场效应

Xiaojie Xue, Takenobu Suzuki, Y. Ohishi
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引用次数: 0

摘要

采用溶剂热法合成了油酸酯包封的α-NaYF4:Nd3+纳米晶体。通过配体交换法,油酸酯包封的纳米碳纳米管可以转化为柠檬酸酯包封的纳米碳纳米管,并可在极性溶剂中分散。通过测量的发射寿命与含碳复合材料有效折射率之间的关系,研究了局域场效应。发现在非极性溶剂体系中,当粒径减小到6 nm时,优选模型由实腔模型变为虚腔模型,而在极性溶剂体系中,优选模型仍为实腔模型。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Local field effect on Nd3+-doped α-NaYF4 nanocrystals in liquids
The oleate-capped α-NaYF4:Nd3+ nanocrystals (NCs) were synthesized via solvothermal method. By a ligand exchange method, the oleate-capped NCs could be changed to citrate-capped samples which can be dispersed in polar solvents. By the relation between the measured emission lifetime and effective refractive indices of the composites containing NCs, the local field effect was investigated. It was found that the preferable model would change from the real cavity model to virtual cavity model when the particle size reduced to 6 nm in nonpolar solvent system, but the preferable model kept being real cavity model in polar solvent system.
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