铜(I)-二醇通过()-O键形成催化1,4-苯并恶硫汀的多米诺合成

Chiranjeevi Korupalli, Arpan Dandapat, D. Prasad, G. Sekar
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引用次数: 3

摘要

1,4-苯并恶硫汀基团的合成方法为:环氧化物与邻卤代酚进行多米诺SN2开环,然后由铜(I)-BINOL催化ullmann型偶联环化(分子内C(芳基)-O键形成),产率中高。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Copper(I)-BINOL Catalyzed Domino Synthesis of 1,4-Benzoxathiines through ()-O Bond Formation
1,4-benzoxathiine moieties can be synthesized by domino SN2 ring opening of epoxide with o-halothiophenols followed by the copper(I)-BINOL catalyzed Ullmann-type coupling cyclization (intramolecular C(aryl)-O bond formation) with moderate to good yields.
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