水溶性Cu(II)酞菁配合物的合成与表征

Synthesis and Reactivity in Inorganic and Metal-organic Chemistry Pub Date : 2004-07-01 DOI:10.1081/SIM-120037523

B. Wang, H.‐Zh. Ma

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引用次数: 9

摘要

摘要合成了八羧酸酞菁铜(II)配合物CuPc(COONa)8及其吡啶取代物CuPc(COONa)8(L)2 (L = Py, 4‐MePy)，并通过元素分析、摩尔电导、IR、1H NMR和电子光谱研究对其进行了表征。提出了一个Pc分子以四齿方式与金属离子配位的结构。

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Synthesis and Characterization of Water‐Soluble Cu(II) Phthalocyanine Complexes

Abstract Octa‐carboxylate phthalocyanine Cu(II) complex, CuPc(COONa)8, and their pyridine substitutes CuPc(COONa)8(L)2 (L = Py, 4‐MePy), have been synthesized and characterized on the basis of elemental analyses, molar conductance, IR, 1H NMR, and electronic spectral studies. A structure is proposed in which one Pc molecule is coordinated to a metal ion in a tetradentate fashion.

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Synthesis and Reactivity in Inorganic and Metal-organic Chemistry

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