一个新的五杂环系:环丁[4,5]吡咯[1,2- A][1,10]菲罗啉

F. Dumitrascu, M. Caira, L. Barbu, B. Miu, B. Draghici
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引用次数: 0

摘要

由2,9-二甲基-1,10-菲罗啉与二甲基乙酰二羧酸盐缩合得到了新的杂环体系环丁基[4,5]吡咯罗[1,2- A][1,10]菲罗啉的衍生物,并通过x射线分析确定了其结构。在这个五杂环框架中观察到的张力分子构象可以归因于一系列排斥的分子内相互作用,这些相互作用使得菲罗啉体系和四元环都是非平面的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A New Pentaheterocyclic System: Cyclobuta[4,5]pyrrolo[1,2-a][1,10]phenanthroline
A derivative of the new heterocyclic system cyclobuta[4,5]pyrrolo[1,2-a][1,10]phenanthroline was obtained by condensation between 2,9-dimethyl-1,10-phenanthroline and dimethyl acetylenedicarboxylate, and its structure was assigned by X-ray analysis. The strained molecular conformation observed for this pentaheterocyclic framework can be attributed to a series of repulsive intramolecular interactions that render both the phenanthroline system and the four-membered ring non-planar.
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