(HgBa2Ca2Cu2.85La0.15O8+δ)化合物的制备及(In2O3)部分取代汞对结构特性的影响研究

E. Hassan, Haider M.J. Haider
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引用次数: 0

摘要

在目前的工作中,我们主要研究(Hg)位点氧化铟部分取代对(0,0.05,0.1,0.15,0.2和0.25)(HgBa2Ca2Cu2.85La0.15O8+δ)化合物结构特性的影响。采用SSR法制备样品。在每平方厘米7吨的压力下粉碎混合粉末,形成厚度为0.2厘米,直径为1.5厘米的圆盘。样品在从环境温度到820°C的变化速率下烧结24小时。对于掺杂(In=0.05)的样品,与其他样品相比,通过(XRD)分析发现c轴晶格参数最高,并具有伪四方结构。我们发现,改变样品中所有结果中的In浓度会改变体积分数VPh(1223)、质量密度dm和c/a。还确定了晶格参数、结晶度、晶体尺寸和应变(以不同的方式)的变化是由氧化铟浓度的变化引起的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation (HgBa2Ca2Cu2.85La0.15O8+δ) compound and Study of the impact of partial substitution of mercury with (In2O3)on the structural characteristics
In the current work, we focused on the impact of Indium oxide partial substitution at the (Hg) site on the structural characteristics of the (HgBa2Ca2Cu2.85La0.15O8+δ) compound with (0,0.05,0.1,0.15,0.2 and 0.25).  Samples were prepared by the (SSR) method. The combined powder was crushed with a pressure of 7 tons per square centimeter to create a disc with a thickness of (0.2 cm) and a diameter of (1.5 cm). The samples sintered for 24 hours at a rate that was changed from ambient temperature to 820 °C. For the samples which were doped with (In=0.05) in comparison to other samples, the highest value of the c-axis lattice parameter and a pseudo-tetragonal structure were discovered using (XRD) analysis. It was discovered that altering the In concentrations in all of the results of our sample changes the volume fraction VPh(1223), mass density dm, and  c/a. It was also determined that the change in lattice parameters, degree of crystallinity, crystal size, and strain (in different ways) resulted from a change in the indium oxide concentrations for all samples.
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