链式聚合中聚合速率常数与单体结构及活性中心的关系

Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics Pub Date : 1986-02-01 DOI:10.1080/07366578608081967

K. Matyjaszewski

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引用次数: 12

摘要

构效关系是化学中最基本的问题之一。在有机化学中，取代基的结构对化学反应速率和平衡常数的影响首先被定量地建立起来，并以著名的哈米特方程的形式表现出来。

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CORRELATION OF THE RATE CONSTANTS OF PROPAGATION WITH THE STRUCTURES OF MONOMERS AND ACTIVE CENTERS IN CHAIN-GROWTH POLYMERIZATION

Abstract Structure-reactivity correlation is one of the most fundamental problems in chemistry. In organic chemistry the influence of the structure of substituents on the rate and equilibrium constants of chemical reactions was first quantitatively established and presented in the form of the well-known Hammett equation.

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Journal of Macromolecular Science-reviews in Macromolecular Chemistry and Physics

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