钙钛矿锰矿:在室温或接近室温下进行磁冷却的潜在材料

Y. Xu , M. Meier , P. Das , M.R. Koblischka , U. Hartmann
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引用次数: 96

摘要

钙钛矿锰矿是一种功能材料,具有巨大的磁阻,可用作磁传感器。本文报道了La0.67Ca0.33MnO3、La0.67Sr0.33MnO3和La0.67Ba0.33MnO3多晶块体材料的合成和表征。对这些样品的磁化强度随温度和磁场的变化进行了详细测量。在居里温度附近,磁化数据得到了显著的熵变。这些样品在其相变温度附近的比热变化是由磁测量得出的。总结了我们的研究结果和各种文献的相关数据。进一步评价了钙钛矿锰矿材料的磁热效应及其在磁冷却中的潜在应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Perovskite manganites: potential materials for magnetic cooling at or near room temperature

Perovskite manganites are known as functional materials showing colossal magnetoresistance and are used as magnetic sensors. We report on the synthesis and characterization of La0.67Ca0.33MnO3, La0.67Sr0.33MnO3, and La0.67Ba0.33MnO3 polycrystalline bulk materials. Detailed measurements of the magnetization as function of temperature and magnetic field for these samples were carried out. Significant entropy changes near the Curie temperatures are obtained from the magnetization data. The specific heat changes of these samples near their phase transition temperatures are derived from magnetic measurements. Our results and the relevant data from various references are summarized. Furthermore the magnetocaloric effects and potential applications in magnetic cooling of perovskite manganite materials are evaluated.

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