提高金属-有机骨架电导率和离子电导率的策略

IF 3.8 3区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Comments on Inorganic Chemistry Pub Date : 2020-03-03 DOI:10.1080/02603594.2019.1704738

M. A. Gordillo, S. Saha

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引用次数: 8

摘要

由于其高度有序的晶体结构和易于引入不同的电活性元离子和配体，金属有机框架(mof)已成为一种有前途的导电和离子导电材料。在这篇小型综述中，我们重点介绍了mof(否则是绝缘体或不良导体)的客体诱导电子和离子电导率的最新进展。讨论了客体诱导框架氧化或还原、π-供体/受体堆叠形成、配位不饱和节点交联以及移动Li+和Mg2+与mof的结合等增强电导率的例子。图形抽象

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Strategies to Improve Electrical and Ionic Conductivities of Metal–Organic Frameworks

ABSTRACT Owing to their highly ordered crystalline structures and ease of introducing different electroactive meta ions and ligands, metal–organic frameworks (MOFs) have emerged as promising electrical and ion conducting materials. In this minireview, we highlighted recent advances in guest-induced electronic and ionic conductivity of MOFs, which are otherwise insulators or poor conductors. Examples of conductivity enhancement upon guest-induced framework oxidation or reduction, π-donor/acceptor stack formation, crosslinking of coordinatively unsaturated nodes, and binding of mobile Li+ and Mg2+ with the MOFs are discussed. Graphical abstract

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来源期刊

Comments on Inorganic Chemistry 化学-无机化学与核化学

CiteScore

9.00

自引率

1.90%

发文量

审稿时长

>12 weeks

期刊介绍： Comments on Inorganic Chemistry is intended as a vehicle for authoritatively written critical discussions of inorganic chemistry research. We publish focused articles of any length that critique or comment upon new concepts, or which introduce new interpretations or developments of long-standing concepts. “Comments” may contain critical discussions of previously published work, or original research that critiques existing concepts or introduces novel concepts. Through the medium of “comments,” the Editors encourage authors in any area of inorganic chemistry - synthesis, structure, spectroscopy, kinetics and mechanisms, theory - to write about their interests in a manner that is both personal and pedagogical. Comments is an excellent platform for younger inorganic chemists whose research is not yet widely known to describe their work, and add to the spectrum of Comments’ author profiles, which includes many well-established inorganic chemists.