退火对溶胶-凝胶法制备ZnO:Mn薄膜光致发光的影响

Wei Yu, Zi-cai Zhang, Kun Zhang, Xiaoyun Teng, Shujie Wu, Li Zhang, Mingjing Chen, G. Fu
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引用次数: 2

摘要

采用溶胶-凝胶法制备了ZnO:Mn薄膜。研究了退火时间对所制备薄膜光致发光性能的影响。ZnO:Mn薄膜的室温PL由自由激子的辐射重组引起的紫外发射带和从Zn空位(VZn)到氧对位的辐射转变引起的弱绿带组成。结果表明,随着退火时间的延长,两种发光带的相对强度都有所增加,但绿色发光的相对强度比紫外发光的相对强度有所增强。同时,饱和磁化强度也有所增加。结果表明,虽然退火对ZnO:Mn薄膜的微观结构有改善作用,但伴随而来的VZn缺陷的增加使其磁矩更加排列。Keywords-sol-gel;ZnMnO;PL;铁磁性;却
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Influence of Annealing on Photoluminescence of ZnO:Mn Thin Flims Grown by Sol-Gel Technique
ZnO:Mn thin flims were fabricated by Sol-gel technique. the effect of annealing time on the photoluminescence (PL) properties of the prepared flims has been investigated. The room temperature PL of ZnO:Mn films is shown to consist of an UV emission band due to radiative recombination of free excitons and a weak green band signated as the radiative transition from Zn vacancies(VZn) to Oxygen antisites. It is shown that whereas increasing annealing time make both of emission bands increase, an enhacement for the relative intensity of green emission compared to that of UV emission is obtend. Meanwhile, An increse of saturation magnetizations was also observed. All results provided clear evidences that although the annealing have the effect of ameliorate the microstructure of ZnO:Mn flim, the accompanied increased VZn defects make the magnetic moments become more alignd. Keywords-sol-gel; ZnMnO; PL; ferromagnetism; VZn
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