铕掺杂ZnO纳米粒子与Li共掺杂对结构-光学性质关系的显著影响

IF 2.9 4区材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Technology Pub Date : 2023-09-03 DOI:10.1080/10667857.2023.2253646

Ashok Kumawat, S. Chattopadhyay, K. Misra

{"title":"铕掺杂ZnO纳米粒子与Li共掺杂对结构-光学性质关系的显著影响","authors":"Ashok Kumawat, S. Chattopadhyay, K. Misra","doi":"10.1080/10667857.2023.2253646","DOIUrl":null,"url":null,"abstract":"ABSTRACT We describe here the structural evolution and optical properties of co-doping of Eu-doped ZnO nanoparticles with lithium synthesized by the sol-gel process. The characterization was carried out via X-ray diffraction (XRD), Fourier transmission infrared (FTIR), UV-Vis spectroscopy, and photoluminescence (PL) techniques. XRD confirmed hexagonal wurtzite phase of ZnO nanoparticles with crystallite size in the range of 22–61 nm. The band gap calculated from UV-vis spectra was in the range of 3.30–3.26 eV for undoped and Li and Eu co-doped ZnO nanoparticles, respectively, while photoluminescence study indicated that Li in Eu-ZnO affected the PL emission intensity, which was attributed to defects present in the crystal lattice. The field emission scanning electron microscopy (FESEM) images revealed the diverse morphology containing, spherical, tri-, tetra-, penta- and hexagonal rod-like nanostructures.","PeriodicalId":18270,"journal":{"name":"Materials Technology","volume":"49 1","pages":""},"PeriodicalIF":2.9000,"publicationDate":"2023-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Significant impact of co-doping Eu-doped ZnO nanoparticles with Li on structural–optical properties relationship\",\"authors\":\"Ashok Kumawat, S. Chattopadhyay, K. Misra\",\"doi\":\"10.1080/10667857.2023.2253646\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT We describe here the structural evolution and optical properties of co-doping of Eu-doped ZnO nanoparticles with lithium synthesized by the sol-gel process. The characterization was carried out via X-ray diffraction (XRD), Fourier transmission infrared (FTIR), UV-Vis spectroscopy, and photoluminescence (PL) techniques. XRD confirmed hexagonal wurtzite phase of ZnO nanoparticles with crystallite size in the range of 22–61 nm. The band gap calculated from UV-vis spectra was in the range of 3.30–3.26 eV for undoped and Li and Eu co-doped ZnO nanoparticles, respectively, while photoluminescence study indicated that Li in Eu-ZnO affected the PL emission intensity, which was attributed to defects present in the crystal lattice. The field emission scanning electron microscopy (FESEM) images revealed the diverse morphology containing, spherical, tri-, tetra-, penta- and hexagonal rod-like nanostructures.\",\"PeriodicalId\":18270,\"journal\":{\"name\":\"Materials Technology\",\"volume\":\"49 1\",\"pages\":\"\"},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2023-09-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1080/10667857.2023.2253646\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Technology","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/10667857.2023.2253646","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 1

摘要

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Significant impact of co-doping Eu-doped ZnO nanoparticles with Li on structural–optical properties relationship

ABSTRACT We describe here the structural evolution and optical properties of co-doping of Eu-doped ZnO nanoparticles with lithium synthesized by the sol-gel process. The characterization was carried out via X-ray diffraction (XRD), Fourier transmission infrared (FTIR), UV-Vis spectroscopy, and photoluminescence (PL) techniques. XRD confirmed hexagonal wurtzite phase of ZnO nanoparticles with crystallite size in the range of 22–61 nm. The band gap calculated from UV-vis spectra was in the range of 3.30–3.26 eV for undoped and Li and Eu co-doped ZnO nanoparticles, respectively, while photoluminescence study indicated that Li in Eu-ZnO affected the PL emission intensity, which was attributed to defects present in the crystal lattice. The field emission scanning electron microscopy (FESEM) images revealed the diverse morphology containing, spherical, tri-, tetra-, penta- and hexagonal rod-like nanostructures.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Materials Technology 工程技术-材料科学：综合

CiteScore

6.00

自引率

9.70%

发文量

105

审稿时长

8.7 months

期刊介绍： Materials Technology: Advanced Performance Materials provides an international medium for the communication of progress in the field of functional materials (advanced materials in which composition, structure and surface are functionalised to confer specific, applications-oriented properties). The focus is on materials for biomedical, electronic, photonic and energy applications. Contributions should address the physical, chemical, or engineering sciences that underpin the design and application of these materials. The scientific and engineering aspects may include processing and structural characterisation from the micro- to nanoscale to achieve specific functionality.