{"title":"含Ijero-Ekiti煅烧高岭土和磨砂废窗玻璃的二元混合地聚合物粘结剂的潜力","authors":"M. B. Ogundiran, Festus Abodunde Winjobi","doi":"10.5897/AJPAC2015.0640","DOIUrl":null,"url":null,"abstract":"The aim of this study was to investigate alkaline reactivity potentials of calcined clay and ground waste window glass with NaOH/Na2SiO3 solution to form geopolymer, an inorganic binder. A calcined clay (CC) sourced from Ijero-Ekiti, Nigeria, was replaced by various proportions (0, 25, 50 and 75%) of ground waste window glass (GWWG) and subjected to alkaline activation by NaOH/Na2SiO3 solution. X-ray florescence (XRF) and Fourier Transform Infrared (FTIR) spectroscopy were applied to characterise the materials and the resulting geopolymers. The XRF results revealed the main oxides of Ijero-Ekiti clay as SiO2 and Al2O3 and for GWWG as SiO2 and Na2O. The FTIR results confirm the clay as kaolin clay which is suitable for geopolymer synthesis. The synthesised geopolymer binders were cured at room temperature for 7, 14, 21 and 28 days. Their compressive strengths, dry density and water absorption were measured. Geopolymers with ground waste window glass (GWWG) indicated higher strengths at both early and late curing times. The final 28-day compressive strength values of GWWG-CC-based geopolymers observed was in the range of 17.3±0.6 to 23.1±0.7 MPa compared with 11.6±0.4 to 14.5±1.4 MPa for 100% CC-geopolymers. Calcined clay replacement up to 75% glass yielded the highest strength. Addition of window waste glass enhanced both early and late strength gain of the geopolymers and improved physical properties. Therefore, GWWG-CC-geopolymers could serve as potential binders in making green construction and building materials. \n \n \n \n Key words: Ijero-Ekiti kaolin clay, waste window glass, recycling, clay-waste-glass-geopolymer, compressive strength development.","PeriodicalId":7556,"journal":{"name":"African Journal of Pure and Applied Chemistry","volume":"9 1","pages":"159-166"},"PeriodicalIF":0.0000,"publicationDate":"2015-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"15","resultStr":"{\"title\":\"The potential of binary blended geopolymer binder containing Ijero-Ekiti calcined kaolin clay and ground waste window glass\",\"authors\":\"M. B. 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Their compressive strengths, dry density and water absorption were measured. Geopolymers with ground waste window glass (GWWG) indicated higher strengths at both early and late curing times. The final 28-day compressive strength values of GWWG-CC-based geopolymers observed was in the range of 17.3±0.6 to 23.1±0.7 MPa compared with 11.6±0.4 to 14.5±1.4 MPa for 100% CC-geopolymers. Calcined clay replacement up to 75% glass yielded the highest strength. Addition of window waste glass enhanced both early and late strength gain of the geopolymers and improved physical properties. Therefore, GWWG-CC-geopolymers could serve as potential binders in making green construction and building materials. \\n \\n \\n \\n Key words: Ijero-Ekiti kaolin clay, waste window glass, recycling, clay-waste-glass-geopolymer, compressive strength development.\",\"PeriodicalId\":7556,\"journal\":{\"name\":\"African Journal of Pure and Applied Chemistry\",\"volume\":\"9 1\",\"pages\":\"159-166\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2015-07-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"15\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"African Journal of Pure and Applied Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.5897/AJPAC2015.0640\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"African Journal of Pure and Applied Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.5897/AJPAC2015.0640","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 15
摘要
本研究的目的是研究煅烧粘土和磨碎废窗玻璃与NaOH/Na2SiO3溶液形成无机粘结剂地聚合物的碱性反应电位。一种来自尼日利亚Ijero-Ekiti的煅烧粘土(CC)被不同比例(0、25、50和75%)的地面废窗玻璃(GWWG)所取代,并通过NaOH/Na2SiO3溶液进行碱性活化。采用x射线荧光(XRF)和傅里叶变换红外(FTIR)光谱对材料和所得地聚合物进行了表征。XRF结果表明,Ijero-Ekiti粘土的主要氧化物为SiO2和Al2O3, GWWG的主要氧化物为SiO2和Na2O。FTIR结果证实该粘土为高岭土,适合用于地聚合物的合成。将合成的地聚合物粘结剂室温固化7、14、21和28天。测定了其抗压强度、干密度和吸水率。含废玻璃的地聚合物在养护初期和后期均表现出较高的强度。gwwg - cc基地聚合物的最终28天抗压强度值在17.3±0.6至23.1±0.7 MPa之间,而100% cc基地聚合物的最终28天抗压强度为11.6±0.4至14.5±1.4 MPa。煅烧粘土替代高达75%的玻璃产生最高的强度。废玻璃的加入提高了地聚合物的早期和后期强度增益,并改善了物理性能。因此,gwwg - cc -地聚合物可以作为潜在的粘合剂用于绿色建筑和建筑材料。关键词:Ijero-Ekiti高岭土,废窗玻璃,回收利用,粘土-废玻璃地聚合物,抗压强度发展
The potential of binary blended geopolymer binder containing Ijero-Ekiti calcined kaolin clay and ground waste window glass
The aim of this study was to investigate alkaline reactivity potentials of calcined clay and ground waste window glass with NaOH/Na2SiO3 solution to form geopolymer, an inorganic binder. A calcined clay (CC) sourced from Ijero-Ekiti, Nigeria, was replaced by various proportions (0, 25, 50 and 75%) of ground waste window glass (GWWG) and subjected to alkaline activation by NaOH/Na2SiO3 solution. X-ray florescence (XRF) and Fourier Transform Infrared (FTIR) spectroscopy were applied to characterise the materials and the resulting geopolymers. The XRF results revealed the main oxides of Ijero-Ekiti clay as SiO2 and Al2O3 and for GWWG as SiO2 and Na2O. The FTIR results confirm the clay as kaolin clay which is suitable for geopolymer synthesis. The synthesised geopolymer binders were cured at room temperature for 7, 14, 21 and 28 days. Their compressive strengths, dry density and water absorption were measured. Geopolymers with ground waste window glass (GWWG) indicated higher strengths at both early and late curing times. The final 28-day compressive strength values of GWWG-CC-based geopolymers observed was in the range of 17.3±0.6 to 23.1±0.7 MPa compared with 11.6±0.4 to 14.5±1.4 MPa for 100% CC-geopolymers. Calcined clay replacement up to 75% glass yielded the highest strength. Addition of window waste glass enhanced both early and late strength gain of the geopolymers and improved physical properties. Therefore, GWWG-CC-geopolymers could serve as potential binders in making green construction and building materials.
Key words: Ijero-Ekiti kaolin clay, waste window glass, recycling, clay-waste-glass-geopolymer, compressive strength development.