多壁碳纳米管的功能化研究

Chunwei Yang, Xin-guo Hu, Yong Zhang
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引用次数: 4

摘要

提出了一种简便的多壁碳纳米管(MWCNTs)表面氧化的方法,使用氧化溶液修饰MWCNTs,超声促进这种效果并增加表面氧化基团的密度。超声短时间氧化/功能化是最小化MWCNTs结构损伤(可能导致其性能变化)的理想选择。XPS、IR和拉曼光谱的测量结果证实MWCNTs上修饰了大量官能团。在MWCNTs氧化过程中,在MWCNTs表面形成羟基、羰基和羧基。在硝酸和硫酸中处理的MWCNTs比在过氧化氢和硫酸中处理的MWCNTs具有更多的官能团
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A Study of the Functionalization on Multi-walled Carbon nanotubes
A facile approach to the surface oxidation of multi-walled carbon nanotubes (MWCNTs) is presented using oxidation solution to decorating MWCNTs, sonication to promote this effect and increase the population density of surface oxide groups. The sonication short time for MWCNTs oxidation /functionalization is desirable for minimizing structural damage to the MWCNTs that could lead to changes in their properties. The measurement results of XPS, IR and Raman spectrum have verified that a great lot of functional groups had been decorated on MWCNTs. During the MWCNTs oxidation, the hydroxy, carbonyl and carboxy formed on the surface of MWCNTs. MWCNTs treated in the nitric and sulfuric acids had more functional groups than MWCNTs treated in hydrogen peroxide and sulfuric acids
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