K. Emran, Arwa O. Al-Ahmadi, Bayan A. Torjoman, N. M. Ahmed, Sara N. Sheekh
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引用次数: 9
摘要
采用析氢法(HEM)和失重法(MLM)研究了哈密瓜汁和种子提取物对铸铁在1.0 M盐酸(HCl)溶液中腐蚀的影响。哈密瓜提取物对铸铁在1.0 M HCl溶液中的腐蚀有抑制作用。随着提取物浓度的增加,其抑菌效果逐渐增强。抑制剂分子在铸铁表面的吸附符合Langmuir吸附等温线。在没有抑制剂的情况下,随着HCl浓度的增加,铸铁的腐蚀速率增加。在HCl溶液中观察到的分数级反应顺序表明中间体的形成是通过溶解过程或铸铁在HCl溶液中溶解的多步骤机制。关键词:甜瓜,腐蚀,铸铁,HCl浓度,吸附等温线
Corrosion and corrosion inhibition of cast Iron in hydrochloric acid (HCl) solution by cantaloupe (Cucumis melo) as green inhibitor
The effect of cantaloupe juice and seed extracts on corrosion of cast iron in 1.0 M hydrochloric acid (HCl) solution using hydrogen evolution measurements (HEM) and mass loss measurements (MLM) were investigated. Cantaloupe extracts inhibited the corrosion of cast iron in 1.0 M HCl solution. The inhibition efficiency increased with concentration of the extracts. The adsorption of the inhibitor molecules on cast iron surface was in accordance to Langmuir adsorption isotherms. In absence of inhibitors, the corrosion rate of cast iron increases with HCl concentration. The fractional reaction order observed in HCl solution indicates the formation of intermediates through the dissolution process or multiple steps mechanism of cast iron dissolution in HCl solution.
Key words: Cantaloupe (Cucumis melo), corrosion, cast iron, HCl concentrations, adsorption isotherm.