不饱和末端环氧化物的分子内环丙烷化反应

IF 14.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of the American Chemical Society Pub Date : 2004-06-24 DOI:10.1021/ja047346k

David M. Hodgson, Ying Kit Chung, Jean-Marc Paris

引用次数: 52

摘要

描述了锂酰胺诱导的双聚和三聚环氧化合物的分子内环丙烷化反应。该方法用于不对称合成萨比娜酮。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Intramolecular Cyclopropanation of Unsaturated Terminal Epoxides

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Intramolecular Cyclopropanation of Unsaturated Terminal Epoxides

Efficient lithium amide-induced intramolecular cyclopropanation of bishomoallylic and trishomoallylic epoxides is described. The methodology is used in an asymmetric synthesis of sabina ketone.

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来源期刊

Journal of the American Chemical Society 化学-化学综合

CiteScore

24.40

自引率

6.00%

发文量

2398

审稿时长

1.6 months

期刊介绍： The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.