紫外光降解亚甲基蓝的ZnO/VNC材料

A. Arunkumar, T. Chandrasekaran, K. Ahamed
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引用次数: 0

摘要

氧化锌材料作为光催化反应,导致有机污染物部分或完全矿化或脱色。在紫外/可见光照射下,半导体催化剂在空气/O2和水的存在下发生氧化还原反应。在本研究中,氧化锌(ZnO)掺杂了由植物材料的茎经化学活化制备的活性炭,即牡荆茎碳(VNC)。通过对亚甲基蓝(MB)染料的脱色和降解研究,考察了ZnO/VNC的催化性能。在含ZnO/VNC材料的20、40、60 ppm染料溶液中,每隔10 min进行反应。研究发现,制备的ZnO / VNC复合材料在可见光照射下对MB的降解表现出增强的光催化活性,并利用紫外-可见分光光度计在特定的663nm λ max下分析了其光催化效率。采用FT-IR、SEM和XRD对ZnO / VNC材料的表面形貌和官能团进行了表征。结果表明,ZnO/VNC结构由表面粗糙的不规则聚集体组成,ZnO/VNC对MB溶液的光降解活性在20ppm时较高。ZnO/VNC可以作为一种替代吸附剂从水溶液中去除MB。关键词:亚甲基蓝,ZnO / VNC, FT-IR, SEM, XRD
本文章由计算机程序翻译,如有差异,请以英文原文为准。
ZnO/VNC Material for UV-Photodegradation of Methylene Blue
ZnO materials act as a Photocatalytic reaction and it leads to partial or complete mineralization or decolorization of organic pollutants. Upon irradiation with UV/visible light, semiconductors catalyze undergoes redox reactions in presence of air/O2 and water. In the present study Zinc oxide (ZnO) was doped with activated carbon prepared from the stem of the plant material by chemical activation namely, Vitexnegundo stem carbon (VNC). The decolourisation and degradation study of a dye namely, methylene blue (MB) was carried out to find out the efficiency of catalytic property of ZnO/VNC. The reaction was performed at 20, 40, 60 ppm of dye solution with ZnO/VNC material at 10 min interval of time. It found that the prepared ZnO / VNC composite exhibits an enhanced Photocatalytic activity for MB degradation under visible light irradiation and its photo catalysis efficiency was analyzed in specific 663 nm λ max using a UV–vis-spectrophotometer. The surface morphology and functional group present in the ZnO / VNC material was characterized by using FT-IR, SEM and XRD. The result reveals that the ZnO/VNC structure consists of irregular aggregates with rough surfaces and high photodegradation activities of ZnO/VNC on MB solutions are found to be at 20ppm. The ZnO/VNC may be used as an alternative adsorbent to remove MB from aqueous solutions.Keywords: Methylene blue (MB), ZnO / VNC, FT-IR, SEM, XRD
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