Xu Yingying, Laijin Tian, Wenchao Ding, Han Lu, Wugai An
{"title":"1.2.5. 2-甲氧基羰基乙基二氯锡的合成、晶体结构和催化活性","authors":"Xu Yingying, Laijin Tian, Wenchao Ding, Han Lu, Wugai An","doi":"10.21060/cis.v1i2.2001","DOIUrl":null,"url":null,"abstract":"Abstract: 2-methoxycarbonylethyldichlorotin hydroxide, CH 3 OCOCH 2 CH 2 SnCl 2 (OH) ( 1), has been synthesized by hydrolysis reaction and characterized by elemental analysis, FTIR, 1 H NMR spectroscopy, and X-ray single crystal diffraction. Compound 1 is a centrosymmetric dimmer, and the tin atom approximates to octahedral geometry via an intramolecular carbonyl- to-tin coordination and hydroxo-bridging. The compound display high selectivity and good catalysis activity on the transesterification reaction of ethyl acetoacetate with an alcohol. Supporting information: FT-IR, 1 H NMR, X-Ray, GC/MS analyses, Cif file.","PeriodicalId":10648,"journal":{"name":"Communications in Inorganic Synthesis","volume":"43 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2015-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"1.2.5. Synthesis, crystal structure and catalytic activity of 2-methoxycarbonylethyldichlorotin hydroxide\",\"authors\":\"Xu Yingying, Laijin Tian, Wenchao Ding, Han Lu, Wugai An\",\"doi\":\"10.21060/cis.v1i2.2001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract: 2-methoxycarbonylethyldichlorotin hydroxide, CH 3 OCOCH 2 CH 2 SnCl 2 (OH) ( 1), has been synthesized by hydrolysis reaction and characterized by elemental analysis, FTIR, 1 H NMR spectroscopy, and X-ray single crystal diffraction. Compound 1 is a centrosymmetric dimmer, and the tin atom approximates to octahedral geometry via an intramolecular carbonyl- to-tin coordination and hydroxo-bridging. The compound display high selectivity and good catalysis activity on the transesterification reaction of ethyl acetoacetate with an alcohol. Supporting information: FT-IR, 1 H NMR, X-Ray, GC/MS analyses, Cif file.\",\"PeriodicalId\":10648,\"journal\":{\"name\":\"Communications in Inorganic Synthesis\",\"volume\":\"43 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2015-04-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Communications in Inorganic Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.21060/cis.v1i2.2001\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Communications in Inorganic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21060/cis.v1i2.2001","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
1.2.5. Synthesis, crystal structure and catalytic activity of 2-methoxycarbonylethyldichlorotin hydroxide
Abstract: 2-methoxycarbonylethyldichlorotin hydroxide, CH 3 OCOCH 2 CH 2 SnCl 2 (OH) ( 1), has been synthesized by hydrolysis reaction and characterized by elemental analysis, FTIR, 1 H NMR spectroscopy, and X-ray single crystal diffraction. Compound 1 is a centrosymmetric dimmer, and the tin atom approximates to octahedral geometry via an intramolecular carbonyl- to-tin coordination and hydroxo-bridging. The compound display high selectivity and good catalysis activity on the transesterification reaction of ethyl acetoacetate with an alcohol. Supporting information: FT-IR, 1 H NMR, X-Ray, GC/MS analyses, Cif file.
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