食品中碘、碘化物和碘酸盐含量的测定

E. O. Markova, D. A. Nekrasov, Michael Yu. Dyakov, A.A. Danilov
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摘要

目前,碘缺乏症是最重要的医学和社会问题之一。对此,本研究的目的是测定加碘盐、饮用水和矿泉水、海藻中碘、碘化物、碘酸盐的含量,以确定食盐中碘含量的稳定性。为了定性测定海藻中的碘化物和碘酸盐离子及分子碘,进行了碘淀粉反应。用硝酸银与氯水反应,测定了碘化水中碘离子的存在,用氯仿提取了释放的碘。分别用滴定法、比色法和重量法测定了食盐中的碘。研究发现,碘盐中碘以碘酸钾形式存在,碘元素含量为18.65 μg / g,海带中碘元素含量为8.12 μg / g,加碘水中碘元素含量为0.327 μg / ml。研究证明,随着时间的推移,用碘酸钾加碘的盐中的碘含量在一个月后减少了5.6倍。为了符合每日碘的摄取量,你需要在你的饮食中加入约9.7克的碘盐,这超过了每日5克的摄入量。在这方面,建议使用碘盐(不超过5克)或碘化水(0.7升水)或海带(18.47克)来预防缺碘。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Determination of the content of iodine, iodides and iodates in food products
Currently iodine deficiency diseases are one of the most important medical and social problems. In this regard, the purpose of the study is to determine the content of iodine, iodides, iodates in iodized salt, drinking and mineral water, seaweed, to determine the stability of the iodine content in salt. For the qualitative determination of iodides and iodates ions in salts and molecular iodine in seaweed, an iodine starch reaction has been carried out. The presence of iodide ions in iodized water has been determined by reaction with silver nitrate and chlorine water, the iodine released has been extracted with chloroform. Quantitative determination of iodine in salt has been carried out by the titrimetric method, in water – by colorimetric method, in seaweed – by gravimetric method with subsequent titration. The study has found that iodized salt contains iodine in the form of potassium iodate, in an amount of 18.65 μg / g of elemental iodine, kelp contains molecular iodine in the amount of 8.12 μg / g of elemental iodine, and iodized water contains potassium iodide in the amount of 0.327 μg / ml of elemental iodine. The study has proved that over time, the amount of iodine in the salt iodized with potassium iodate decreases after a month by 5.6 times. In order to comply with the daily rate of iodine intake, it is necessary to include in your diet about 9.7 g of iodized salt, which exceeds the daily norm of its consumption in 5 g. In this regard, it is recommended to use iodized salt (not more than 5 g) or iodized water (0.7 L of water) or kelp (18.47 g) as a prevention of iodine deficiency.
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