Xiu-Mei Li, Jian-Ye Ji, Zhi-tao Wang, Yan-Ling Niu
{"title":"1.2.3. [Co0.5(bimb)1.5] n·nClO4 (bimb =1,4-双(咪唑-1-基)-丁烷)的合成与结构表征","authors":"Xiu-Mei Li, Jian-Ye Ji, Zhi-tao Wang, Yan-Ling Niu","doi":"10.21060/cis.v1i2.1999","DOIUrl":null,"url":null,"abstract":"Abstract: A new cobalt(II) coordination polymer, namely [Co 0.5 (bimb) 1.5 ] n ·nClO 4 (bimb =1,4-bis(imidazol-1-yl)-butane) (1), has been prepared and fully characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy and X-ray powder diffraction pattern analysis (PXRD). Of the compound, the Co(II) center is octahedral coordinated with bimb serving as a bridging ligand by employing six N-donor to coordinate with the Co(II) center. It exbihits three-dimensional network structure via bimb ligands. Supporting information: CIF file.","PeriodicalId":10648,"journal":{"name":"Communications in Inorganic Synthesis","volume":"114 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"1.2.3. Synthesis and Structural Characterization of [Co0.5(bimb)1.5] n·nClO4 (bimb =1,4-bis(imidazol-1-yl)-butane)\",\"authors\":\"Xiu-Mei Li, Jian-Ye Ji, Zhi-tao Wang, Yan-Ling Niu\",\"doi\":\"10.21060/cis.v1i2.1999\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract: A new cobalt(II) coordination polymer, namely [Co 0.5 (bimb) 1.5 ] n ·nClO 4 (bimb =1,4-bis(imidazol-1-yl)-butane) (1), has been prepared and fully characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy and X-ray powder diffraction pattern analysis (PXRD). Of the compound, the Co(II) center is octahedral coordinated with bimb serving as a bridging ligand by employing six N-donor to coordinate with the Co(II) center. It exbihits three-dimensional network structure via bimb ligands. Supporting information: CIF file.\",\"PeriodicalId\":10648,\"journal\":{\"name\":\"Communications in Inorganic Synthesis\",\"volume\":\"114 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2013-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Communications in Inorganic Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.21060/cis.v1i2.1999\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Communications in Inorganic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21060/cis.v1i2.1999","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
1.2.3. Synthesis and Structural Characterization of [Co0.5(bimb)1.5] n·nClO4 (bimb =1,4-bis(imidazol-1-yl)-butane)
Abstract: A new cobalt(II) coordination polymer, namely [Co 0.5 (bimb) 1.5 ] n ·nClO 4 (bimb =1,4-bis(imidazol-1-yl)-butane) (1), has been prepared and fully characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy and X-ray powder diffraction pattern analysis (PXRD). Of the compound, the Co(II) center is octahedral coordinated with bimb serving as a bridging ligand by employing six N-donor to coordinate with the Co(II) center. It exbihits three-dimensional network structure via bimb ligands. Supporting information: CIF file.
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