Vladimir Djordjić, Applied, M. Pavić-Čolić, Nikola Spasojević
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Polytropic gas modelling at kinetic and macroscopic levels
In this paper, we consider the kinetic model of continuous type describing a polyatomic gas in two different settings corresponding to a different choice of the functional space used to define macroscopic quantities. Such a model introduces a single continuous variable supposed to capture all the phenomena related to the more complex structure of a polyatomic molecule. In particular, we provide a direct comparison of these two settings, and show their equivalence after the distribution function is rescaled and the cross section is reformulated. We then focus on the kinetic model for which the rigorous existence and uniqueness result in the space homogeneous case is recently proven. Using the cross section proposed in that analysis together with the maximum entropy principle, we establish macroscopic models of six and fourteen fields. In the case of six moments, we calculate the exact, nonlinear, production term and prove its total agreement with extended thermodynamics. Moreover, for the fourteen moments model, we provide new expressions for relaxation times and transport coefficients in a linearized setting, that yield both matching with the experimental data for dependence of the shear viscosity upon temperature and a satisfactory agreement with the theoretical value of the Prandtl number.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.