Feras Mosleh Almowalad Feras Mosleh Almowalad
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摘要

木质素是生物质的主要组成部分,被认为是巨大的能源和碳储备。除了是自然界中含量第二丰富的聚合物外,它还是制浆、造纸和其他林业工业的主要副产品,年产量约为7000万吨。由于木质素具有高度的生物抗逆性,因此未得到充分利用,被认为是一种只能焚烧发电的废物。建立一个以木质素为基础的增值化学品市场是必要的。然而,由于其可再生性、可获得性和丰富的酚类成分,它被认为是一种有吸引力的抗氧化活性替代品。在我们的研究中,所有类型的木质素在AAI测试中显示出2.21 ~ 11.47的值,表明具有较高的抗氧化活性。此外,特殊的化学结构,如氢原子、侧链碳之间的双键以及甲氧基的存在,可以通过清除自由基的方式将抗氧化活性提高2- 3倍。最后,与较低温度下提取的木质素相比,较高温度下(~95℃及以上)提取的木质素表现出更高的ORAC值;ORAC值分别为1072.32 ~ 3119.68和1741.72 ~ 1745.11。本文将进一步阐明木质素的抗氧化性能,它的来源,影响它的因素,以及未来的方向和可能的跨学科的潜在改进。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Solving the lignin waste crisis: Utilization of lignin to produce value- added antioxidant agents: حل أزمة نفايات اللجنين: استخدام اللجنين لإنتاج مضادات أكسدة ذات قيمة مضافة
  Lignin is a major component of biomass that is considered a huge energy and carbon reserve. Aside from being the second most abundant polymer in nature, it is a major by- product of pulping, paper and other forestry- based industries with about 70 million tons per year. Due to it being highly biologically recalcitrant, lignin is underutilized and considered a waste product that is solely incinerated for power generation. Establishment of a market for lignin- based, value- added chemicals was a necessity. Because of its renewable nature, availability, and richness in phenolic component, however, it is considered as an attractive alternative for antioxidant activity. In our research, all types of extracted lignin exhibited a value ranging from 2.21 to 11.47 on the AAI assay suggesting high antioxidant activity. Furthermore, special chemical structures such as hydrogen atoms, double bonds between side chain carbons, as well as the presence of methoxyl groups can increase antioxidant activity by 2- 3 folds via means of radical scavenging. Finally, lignin extracted at higher temperature (~95C and greater) exhibited higher ORAC values compared to lignin extracted at lower temperature; ORAC values of 1072.32 to 3119.68 versus 1741.72 to 1745.11, respectively. This paper is going to shed more light on the lignin antioxidant properties, where it stems from, what affects it, as well as future directions and possible interdisciplinary potential improvement.    
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