{"title":"核Cu (II)配合物的合成、结构表征及电化学性能","authors":"X. Tai, Xin Wang, L. Liu","doi":"10.2174/1874088X01509010210","DOIUrl":null,"url":null,"abstract":"A novel dinuclear Cu(II) complex material has been synthesized by the reaction of 1, 2-phenylenedioxydiacetic acid, 1,10-phenantroline (phen) and Cu(CH 3 COO) 2 ·H 2 O. And it has been characterized by elemental analysis, IR, UV and single crystal X-ray diffraction. The crystal belongs to tetragonal, space group I4 1 /a with a = b = 25.381(4) A, c = 32.044(6) A, V = 20643(6) A 3 , Z = 16, D c = 1.395 g·cm −3 , µ = 0.898 mm −1 , F (000) = 8896, and final R = 0.1026, ωR = 0.3142. The structural analysis shows that two Cu(II) atoms adopt different coordination modes, Cu 1 has five-coordination with a trigonal bipyramidal configuration, and Cu 2 has four-coordination with a distorted square planar configuration. The cyclic voltammetric behaviour of the dinuclear Cu(II) complex has been investigated.","PeriodicalId":22791,"journal":{"name":"The Open Materials Science Journal","volume":"25 1","pages":"210-213"},"PeriodicalIF":0.0000,"publicationDate":"2015-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, Structural Characterization and Electrochemical Property of aDinuclear Cu (II) Complex Material\",\"authors\":\"X. Tai, Xin Wang, L. Liu\",\"doi\":\"10.2174/1874088X01509010210\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A novel dinuclear Cu(II) complex material has been synthesized by the reaction of 1, 2-phenylenedioxydiacetic acid, 1,10-phenantroline (phen) and Cu(CH 3 COO) 2 ·H 2 O. And it has been characterized by elemental analysis, IR, UV and single crystal X-ray diffraction. The crystal belongs to tetragonal, space group I4 1 /a with a = b = 25.381(4) A, c = 32.044(6) A, V = 20643(6) A 3 , Z = 16, D c = 1.395 g·cm −3 , µ = 0.898 mm −1 , F (000) = 8896, and final R = 0.1026, ωR = 0.3142. The structural analysis shows that two Cu(II) atoms adopt different coordination modes, Cu 1 has five-coordination with a trigonal bipyramidal configuration, and Cu 2 has four-coordination with a distorted square planar configuration. The cyclic voltammetric behaviour of the dinuclear Cu(II) complex has been investigated.\",\"PeriodicalId\":22791,\"journal\":{\"name\":\"The Open Materials Science Journal\",\"volume\":\"25 1\",\"pages\":\"210-213\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2015-11-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The Open Materials Science Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2174/1874088X01509010210\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Open Materials Science Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/1874088X01509010210","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
以1,2 -苯二氧二乙酸、1,10-菲邻啉(phen)和Cu(ch3 COO) 2·h2o为原料合成了一种新型双核Cu(II)配合物，并用元素分析、IR、UV和单晶x射线衍射对其进行了表征。该晶体属于四边形，空间群为i41 /a, a = b = 25.381(4) a, c = 32.044(6) a, V = 20643(6) a3, Z = 16, D = 1.395 g·cm−3，µ= 0.898 mm−1,F(000) = 8896，终R = 0.1026， ωR = 0.3142。结构分析表明，两个Cu(II)原子采用不同的配位模式，Cu 1具有五配位，具有三角双锥体构型，Cu 2具有四配位，具有扭曲的方形平面构型。研究了双核Cu(II)配合物的循环伏安行为。
Synthesis, Structural Characterization and Electrochemical Property of aDinuclear Cu (II) Complex Material
A novel dinuclear Cu(II) complex material has been synthesized by the reaction of 1, 2-phenylenedioxydiacetic acid, 1,10-phenantroline (phen) and Cu(CH 3 COO) 2 ·H 2 O. And it has been characterized by elemental analysis, IR, UV and single crystal X-ray diffraction. The crystal belongs to tetragonal, space group I4 1 /a with a = b = 25.381(4) A, c = 32.044(6) A, V = 20643(6) A 3 , Z = 16, D c = 1.395 g·cm −3 , µ = 0.898 mm −1 , F (000) = 8896, and final R = 0.1026, ωR = 0.3142. The structural analysis shows that two Cu(II) atoms adopt different coordination modes, Cu 1 has five-coordination with a trigonal bipyramidal configuration, and Cu 2 has four-coordination with a distorted square planar configuration. The cyclic voltammetric behaviour of the dinuclear Cu(II) complex has been investigated.
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