{"title":"酸性铬酸盐与醇的光氧化还原反应:活化自由能与极性能的关系","authors":"I. Iweibo, R.A. Oderinde, J.A. Faniran","doi":"10.1016/0020-1650(81)80066-9","DOIUrl":null,"url":null,"abstract":"<div><p>The rate constant for the photon-activated oxidation of aliphatic alcohols by HCro<sub>4</sub><sup>−</sup> is shown to obey a linear free-energy relation that suggests a two electron-transfer rate-determing step.</p></div>","PeriodicalId":13630,"journal":{"name":"Inorganic and Nuclear Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-1650(81)80066-9","citationCount":"2","resultStr":"{\"title\":\"Photo-redox reaction between acid chromate and alcohols: Correlation of free energy of activation to polar energy\",\"authors\":\"I. Iweibo, R.A. Oderinde, J.A. Faniran\",\"doi\":\"10.1016/0020-1650(81)80066-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The rate constant for the photon-activated oxidation of aliphatic alcohols by HCro<sub>4</sub><sup>−</sup> is shown to obey a linear free-energy relation that suggests a two electron-transfer rate-determing step.</p></div>\",\"PeriodicalId\":13630,\"journal\":{\"name\":\"Inorganic and Nuclear Chemistry Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-1650(81)80066-9\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic and Nuclear Chemistry Letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020165081800669\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic and Nuclear Chemistry Letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020165081800669","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Photo-redox reaction between acid chromate and alcohols: Correlation of free energy of activation to polar energy
The rate constant for the photon-activated oxidation of aliphatic alcohols by HCro4− is shown to obey a linear free-energy relation that suggests a two electron-transfer rate-determing step.
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