{"title":"未改性和化学改性油棕果纤维吸附剂镍离子解吸动力学模型研究","authors":"A. Abia, E. Asuquo, J. C. Igwe","doi":"10.4314/JASET.V7I1.42718","DOIUrl":null,"url":null,"abstract":"The desorption of Ni2+ from three oil palm fruit fibre adsorbents (UOPF, 0.5MOPF and 1.0MOPF) using five desorbing solutions showed a desorption efficiency following the trend, 0.1M HCl > 0.1MH2SO4 > 0.1MHNO3 > 0.1MNaOH >hot deionized H2O. The Elovich desorption constant, β values for the 0.1MHCl desorbent were: 6.45 X10-1, 5.57 x 10-1 and 4.34 x 10-1g. mg-.min-1 for UOPF,0.5MOPF and 1.0MOPF adsorbents respectively. The surface residence time \u001f values for the 0.1MHCl desorbent were; 32.3, 28.6 and 26.8 seconds for UOPF, 0.5MOPF and 1.0MOPF adsorbents respectively. Kinetic modeling analysis of the Elovich and pseudo-first order desorption equations, indicates that the latter model described the desorption of Ni2+ better. Keywords: Nickel, desorption, modeling, kinetics, Elovich, oil palm.","PeriodicalId":7884,"journal":{"name":"Andalasian International Journal of Applied Science, Engineering and Technology","volume":"9 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2009-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Nickel (Ii) Ion Desorption Kinetic Modeling From Unmodified and Chemically Modified Oil Palm (Elaeis Guineensis) Fruit Fibre Adsorbents\",\"authors\":\"A. Abia, E. Asuquo, J. C. Igwe\",\"doi\":\"10.4314/JASET.V7I1.42718\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The desorption of Ni2+ from three oil palm fruit fibre adsorbents (UOPF, 0.5MOPF and 1.0MOPF) using five desorbing solutions showed a desorption efficiency following the trend, 0.1M HCl > 0.1MH2SO4 > 0.1MHNO3 > 0.1MNaOH >hot deionized H2O. The Elovich desorption constant, β values for the 0.1MHCl desorbent were: 6.45 X10-1, 5.57 x 10-1 and 4.34 x 10-1g. mg-.min-1 for UOPF,0.5MOPF and 1.0MOPF adsorbents respectively. The surface residence time \\u001f values for the 0.1MHCl desorbent were; 32.3, 28.6 and 26.8 seconds for UOPF, 0.5MOPF and 1.0MOPF adsorbents respectively. Kinetic modeling analysis of the Elovich and pseudo-first order desorption equations, indicates that the latter model described the desorption of Ni2+ better. Keywords: Nickel, desorption, modeling, kinetics, Elovich, oil palm.\",\"PeriodicalId\":7884,\"journal\":{\"name\":\"Andalasian International Journal of Applied Science, Engineering and Technology\",\"volume\":\"9 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2009-05-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Andalasian International Journal of Applied Science, Engineering and Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4314/JASET.V7I1.42718\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Andalasian International Journal of Applied Science, Engineering and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4314/JASET.V7I1.42718","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Nickel (Ii) Ion Desorption Kinetic Modeling From Unmodified and Chemically Modified Oil Palm (Elaeis Guineensis) Fruit Fibre Adsorbents
The desorption of Ni2+ from three oil palm fruit fibre adsorbents (UOPF, 0.5MOPF and 1.0MOPF) using five desorbing solutions showed a desorption efficiency following the trend, 0.1M HCl > 0.1MH2SO4 > 0.1MHNO3 > 0.1MNaOH >hot deionized H2O. The Elovich desorption constant, β values for the 0.1MHCl desorbent were: 6.45 X10-1, 5.57 x 10-1 and 4.34 x 10-1g. mg-.min-1 for UOPF,0.5MOPF and 1.0MOPF adsorbents respectively. The surface residence time values for the 0.1MHCl desorbent were; 32.3, 28.6 and 26.8 seconds for UOPF, 0.5MOPF and 1.0MOPF adsorbents respectively. Kinetic modeling analysis of the Elovich and pseudo-first order desorption equations, indicates that the latter model described the desorption of Ni2+ better. Keywords: Nickel, desorption, modeling, kinetics, Elovich, oil palm.