钯作为催化剂的研究进展

B. Bhat, Wasseem Akbar Khanday
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引用次数: 0

摘要

本文介绍和讨论了钯催化的C-C交叉偶联反应。有人提出,在钯催化反应中,钯是一个不稳定的、短暂的过渡态,通过简单地稳定过渡态来降低活化能或反应物质。催化剂可以与一种或多种反应物配位,并在催化过程的整个过渡状态中保持配位。在这一过程中,产物的解离要么直接再生Pd,要么产生一种将转化为Pd的物质。这是在有机金属化学中发生的一种典型的酶催化过程。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Palladium used As A Catalyst: A Review
In this review, the most important Pd-catalyzed C-C cross-coupling named reactions have been presented and discussed. It has been proposed that in Pd-catalysed reactions, the Pd decreases the activation energy or reacting species by simply stabilizing the transition state as it is an unstable and short-lived. The catalyst may get coordinated to one or more of the reactants and remains coordinated throughout the transition state of the catalytic process. During this process, the dissociation of the product either regenerates the Pd directly or generates a species that will be converted into the Pd. This is a typical in enzyme–catalyzed processes occurs in organometallic chemistry.
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