对“克拉霉素(形式ӀӀ)在乙醇水溶液中的溶解度测量、热力学建模和溶解度参数”的评论

IF 1.2 4区化学 Q4 CHEMISTRY, PHYSICAL

Physics and Chemistry of Liquids Pub Date : 2023-05-04 DOI:10.1080/00319104.2023.2218525

Ramya Motati, Trisha Kandi, W. E. Acree

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引用次数: 0

摘要

已公布的范霍夫模型曲线拟合方程系数的数值不能描述观测到的摩尔分数溶解度数据。观测到的摩尔分数溶解度和回溯计算的摩尔分数溶解度之间的差异相差多达一个数量级。对已发表的溶解度数据的重新分析得出了完全不同的方程系数集。

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Comments on “Solubility measurement, thermodynamic modeling and solubility parameters of clarithromycin (Form ӀӀ) in aqueous ethanolic solution”

ABSTRACT Published numerical values of the curve-fit equation coefficients of the van’t Hoff model do not describe the observed mole fraction solubility data. Differences between the observed and back-calculated mole fraction solubilities differed by as much as one order of magnitude. Reanalysis of the published solubility data yielded completely different sets of equation coefficients.

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来源期刊

Physics and Chemistry of Liquids 化学-物理：凝聚态物理

CiteScore

3.30

自引率

8.30%

发文量

审稿时长

6-12 weeks

期刊介绍： Physics and Chemistry of Liquids publishes experimental and theoretical papers, letters and reviews aimed at furthering the understanding of the liquid state. The coverage embraces the whole spectrum of liquids, from simple monatomic liquids and their mixtures, through charged liquids (e.g. ionic melts, liquid metals and their alloys, ions in aqueous solution, and metal-electrolyte systems) to molecular liquids of all kinds. It also covers quantum fluids and superfluids, such as Fermi and non-Fermi liquids, superconductors, Bose-Einstein condensates, correlated electron or spin assemblies. By publishing papers on physical aspects of the liquid state as well as those with a mainly chemical focus, Physics and Chemistry of Liquids provides a medium for the publication of interdisciplinary papers on liquids serving its broad international readership of physicists and chemists.