L. Nnanna, Kings O. Uchendu, Glory Ikwuagwu, Wisdom O. John, Uche Ihekoronye
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引用次数: 7
摘要
采用重量法研究了一种生态友好型缓蚀剂——毛毛藻对铝合金AA8011在碱性介质中的缓蚀作用。研究表明,在0.25 M KOH条件下,萃取液使AA8011铝的腐蚀速率从0.407 mm/yr降低到0.106 mm/yr。抑制效果随培养基中植物提取物浓度的增加而增加。实验数据表明Langmuir等温线是低碳钢表面等温线的最佳模型(r2=0.999)。同时计算了吸附的Gibb自由能为15.61 kJmol-1,表明抑制剂分子是通过物理吸附机制自发吸附到铝表面的。
Inhibition of Corrosion of Aluminum Alloy AA8011 in Alkaline Medium Using Palisota hirsute Extract
Gravimetric technique was used to study the inhibition of aluminium alloy AA8011 in an alkaline medium using an eco-friendly inhibitor, Palisota hirsute. The study revealed that the extract reduced the corrosion rate of aluminium AA8011 from 0.407 mm/yr to as low as 0.106 mm/yr in 0.25 M KOH after being exposed for five hours. The inhibition efficiency was found to increase as the concentration of the plant extract in the medium increased. The adsorption studies, computed from the experimental data revealed Langmuir isotherm as the best model for the isotherm (r2=0.999) on the mild steel surface. Gibb’s free energy of adsorption was also calculated and gotten to be 15.61 kJmol-1, suggesting that inhibitor molecules have been spontaneously adsorbed onto the aluminum surface through physical adsorption mechanism.