利用三重态湮没上转换探索锌-苝金属有机骨架、薄膜和体的增强光电流

S. Ahmad, Jinxuan Liu, Licheng Sun
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引用次数: 0

摘要

高结晶表面支撑的金属有机骨架薄膜已被用于光电化学电池中产生增强的光电流。由于三重态湮灭上转换,Zn-perylene SURMOF和吡啶功能化Bodipy的组合光电流比其本身的部分高2倍。这一实验数据表明,MOF薄膜材料非常适合克服染料敏化太阳能电池技术中由于Shockley-Queisser限制而导致的能量损失。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The Exploration of Enhanced Photocurrent with Zn-Perylene Metal Organic Frameworks Thin Film and Bodipy via Triplet Triplet Annihilation Upconversion
Highly crystalline surface supported metal organic framework thin film has been used to generate enhanced photocurrent in the photoelectrochemical cells. The combination of Zn-perylene SURMOF and pyridine functionalized Bodipy has ~ two times higher photocurrent due to triplet triplet annihilation upconversion than its own parts. This experimentally determined data shows that MOF thin film material is well suited for overcoming the energy loss due to Shockley-Queisser limit for dye sensitized solar cell technology.
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