氯化铝配合物的光谱和结构。第四部分:氯化铝高级配合物的结构

Journal of The Chemical Society A: Inorganic, Physical, Theoretical Pub Date : 1971-01-01 DOI:10.1039/J19710003135

D. E. Jones, J. Wood

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引用次数: 3

摘要

用红外光谱和拉曼光谱对配合物AlCl3、2Me2O、AlCl3、1·5MeCN、AlCl3、2MeCN和AlCl31·5HCO2Me进行了表征;模型计算支持AlCl3,2Me2O的三角-双锥体五坐标结构，而其他的则是离子结构。AlCl3,2MeCN在晶格中有未结合的MeCN。

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The spectra and structure of aluminium chloride complexes. Part IV. Structure of higher complexes of aluminium chloride

The complexes AlCl3,2Me2O,AlCl3,1·5MeCN, AlCl3,2MeCN, and AlCl31·5HCO2Me have been examined by i.r. and Raman spectroscopy; model calculations support a trigonal-bipyramidal five-co-ordinate structure for AlCl3,2Me2O but ionic structures are suggested for the others. AlCl3,2MeCN has uncombined MeCN in the crystal lattice.

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Journal of The Chemical Society A: Inorganic, Physical, Theoretical

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