高锰酸盐为氧化剂,甘蔗糖蜜氧化还原反应合成草酸

R. Shaban, M. Abdelwahab, Samia K. Ibrahim
{"title":"高锰酸盐为氧化剂,甘蔗糖蜜氧化还原反应合成草酸","authors":"R. Shaban, M. Abdelwahab, Samia K. Ibrahim","doi":"10.21608/esugj.2021.207983","DOIUrl":null,"url":null,"abstract":"Oxalic acid in alkaline medium was quantitatively synthesized using sugarcane molasse oxidation (SCM) by potassium permanganate as oxidizing agent. The produced compound was identified using Fourier Transform Infrared (FT IR), mass spectra and with by reaction with 2,4-dinitrophenyl hydrazine and hydroxylamine reactions have been identified as the oxidation product (oxalic acid), which gives negative results in 2,4-dinitrophenyl hydrazine and hydroxylamine. It has been found that the oxidation portion has a strong chelation affinity with most monoand divalent complexes that provide stable high chelating agents and therefore one of the most abundant organic acids in the plant. Again, the formic acid was prepared from the result of oxidation (oxalic acid) and by FT IR.","PeriodicalId":11564,"journal":{"name":"Egyptian Sugar Journal","volume":"129 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of Oxalic from Sugarcane Molasses by Oxidation-reduction Reactions using Permanganate Ion as Oxidant\",\"authors\":\"R. Shaban, M. Abdelwahab, Samia K. Ibrahim\",\"doi\":\"10.21608/esugj.2021.207983\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Oxalic acid in alkaline medium was quantitatively synthesized using sugarcane molasse oxidation (SCM) by potassium permanganate as oxidizing agent. The produced compound was identified using Fourier Transform Infrared (FT IR), mass spectra and with by reaction with 2,4-dinitrophenyl hydrazine and hydroxylamine reactions have been identified as the oxidation product (oxalic acid), which gives negative results in 2,4-dinitrophenyl hydrazine and hydroxylamine. It has been found that the oxidation portion has a strong chelation affinity with most monoand divalent complexes that provide stable high chelating agents and therefore one of the most abundant organic acids in the plant. Again, the formic acid was prepared from the result of oxidation (oxalic acid) and by FT IR.\",\"PeriodicalId\":11564,\"journal\":{\"name\":\"Egyptian Sugar Journal\",\"volume\":\"129 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Egyptian Sugar Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.21608/esugj.2021.207983\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Egyptian Sugar Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21608/esugj.2021.207983","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

以高锰酸钾为氧化剂,以甘蔗糖蜜氧化(SCM)为原料,在碱性培养基中定量合成草酸。所得化合物经傅里叶变换红外(FT IR)、质谱鉴定,并与2,4-二硝基苯基肼和羟胺反应,鉴定为氧化产物(草酸),对2,4-二硝基苯基肼和羟胺的反应结果为阴性。已经发现氧化部分与大多数单价和二价配合物具有很强的螯合亲和力,提供稳定的高螯合剂,因此是植物中最丰富的有机酸之一。再用氧化产物(草酸)和红外光谱合成甲酸。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis of Oxalic from Sugarcane Molasses by Oxidation-reduction Reactions using Permanganate Ion as Oxidant
Oxalic acid in alkaline medium was quantitatively synthesized using sugarcane molasse oxidation (SCM) by potassium permanganate as oxidizing agent. The produced compound was identified using Fourier Transform Infrared (FT IR), mass spectra and with by reaction with 2,4-dinitrophenyl hydrazine and hydroxylamine reactions have been identified as the oxidation product (oxalic acid), which gives negative results in 2,4-dinitrophenyl hydrazine and hydroxylamine. It has been found that the oxidation portion has a strong chelation affinity with most monoand divalent complexes that provide stable high chelating agents and therefore one of the most abundant organic acids in the plant. Again, the formic acid was prepared from the result of oxidation (oxalic acid) and by FT IR.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信