{"title":"[Cu3{-(NSPh2)2N}2Cl2]和[Cu3{-(NSPh2)2N}2{(NSPh2)2N}2]Cl2的合成及晶体结构","authors":"T. Fujii, Mihoko Kanno, M. Hirata","doi":"10.1155/2010/326568","DOIUrl":null,"url":null,"abstract":"We have prepared the trinuclear complexes [Cu3{𝜇-(NSPh2)2N}2Cl2] (3) and [Cu3{𝜇-(NSPh2)2N}2{(NSPh2)2N}2]Cl2 (4), from the reaction of CuCl2 with {N(Ph2SN)(Ph2SNH)} (1) and determined their structures by X-ray crystallographic analysis. In both complexes, two monoanions 𝟏− chelate the Cu(II) center in square-planar geometry, whereas the terminal Cu(II) center is four-coordinate and a distorted tetrahedron.","PeriodicalId":14074,"journal":{"name":"International Journal of Inorganic Chemistry","volume":"26 1","pages":"1-6"},"PeriodicalIF":0.0000,"publicationDate":"2010-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Syntheses and Crystal Structures of [Cu3{-(NSPh2)2N}2Cl2] and [Cu3{-(NSPh2)2N}2{(NSPh2)2N}2]Cl2\",\"authors\":\"T. Fujii, Mihoko Kanno, M. Hirata\",\"doi\":\"10.1155/2010/326568\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"We have prepared the trinuclear complexes [Cu3{𝜇-(NSPh2)2N}2Cl2] (3) and [Cu3{𝜇-(NSPh2)2N}2{(NSPh2)2N}2]Cl2 (4), from the reaction of CuCl2 with {N(Ph2SN)(Ph2SNH)} (1) and determined their structures by X-ray crystallographic analysis. In both complexes, two monoanions 𝟏− chelate the Cu(II) center in square-planar geometry, whereas the terminal Cu(II) center is four-coordinate and a distorted tetrahedron.\",\"PeriodicalId\":14074,\"journal\":{\"name\":\"International Journal of Inorganic Chemistry\",\"volume\":\"26 1\",\"pages\":\"1-6\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2010-02-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/2010/326568\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Inorganic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2010/326568","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Syntheses and Crystal Structures of [Cu3{-(NSPh2)2N}2Cl2] and [Cu3{-(NSPh2)2N}2{(NSPh2)2N}2]Cl2
We have prepared the trinuclear complexes [Cu3{𝜇-(NSPh2)2N}2Cl2] (3) and [Cu3{𝜇-(NSPh2)2N}2{(NSPh2)2N}2]Cl2 (4), from the reaction of CuCl2 with {N(Ph2SN)(Ph2SNH)} (1) and determined their structures by X-ray crystallographic analysis. In both complexes, two monoanions 𝟏− chelate the Cu(II) center in square-planar geometry, whereas the terminal Cu(II) center is four-coordinate and a distorted tetrahedron.
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