{"title":"手性辅助定向不对称亲核试剂加成芳烃-锰三羰基配合物选择性逆转的观察","authors":"A. Pearson, M. Milletti, P. Zhu","doi":"10.1039/C39950000853","DOIUrl":null,"url":null,"abstract":"A study of hydride nucleophile reactions with η6-(2R, 5R)-dimethylpyrrolidinylbenzene–manganese tricarbonyl hexafluorophosphate 1 reveals an unexpected reversal of selectivity during addition of hydride to the diastereotopic meta carbons, which is explained on the basis of changes in transition state location as the reactivity of the nucleophile is varied.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"1 1","pages":"853-854"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Observations on selectivity reversal during chiral auxiliary-directed asymmetric nucleophile additions to arene–manganese tricarbonyl complexes\",\"authors\":\"A. Pearson, M. Milletti, P. Zhu\",\"doi\":\"10.1039/C39950000853\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A study of hydride nucleophile reactions with η6-(2R, 5R)-dimethylpyrrolidinylbenzene–manganese tricarbonyl hexafluorophosphate 1 reveals an unexpected reversal of selectivity during addition of hydride to the diastereotopic meta carbons, which is explained on the basis of changes in transition state location as the reactivity of the nucleophile is varied.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"1 1\",\"pages\":\"853-854\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950000853\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950000853","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Observations on selectivity reversal during chiral auxiliary-directed asymmetric nucleophile additions to arene–manganese tricarbonyl complexes
A study of hydride nucleophile reactions with η6-(2R, 5R)-dimethylpyrrolidinylbenzene–manganese tricarbonyl hexafluorophosphate 1 reveals an unexpected reversal of selectivity during addition of hydride to the diastereotopic meta carbons, which is explained on the basis of changes in transition state location as the reactivity of the nucleophile is varied.
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