{"title":"砷局部模态(110 A1/E)波段的高分辨率振动-旋转光谱","authors":"Shengfu Yang, Hai Lin, Doug Wang, Qing-shi Zhu","doi":"10.1039/A708723C","DOIUrl":null,"url":null,"abstract":"The high resolution Fourier transform spectrum of arsine was revisited in the region 4000–4350 cm-1 at a resolution of 0.006 cm-1. Altogether 189 energy levels of the local mode (110 A1/E) states were assigned by use of the ground state combination difference method. The vibration–rotation parameters were obtained from a weighted non-linear least-squares fit and discussed in the local mode model.","PeriodicalId":17286,"journal":{"name":"Journal of the Chemical Society, Faraday Transactions","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1998-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"High resolution vibration–rotation spectra of the arsine local mode (110 A1/E) band\",\"authors\":\"Shengfu Yang, Hai Lin, Doug Wang, Qing-shi Zhu\",\"doi\":\"10.1039/A708723C\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The high resolution Fourier transform spectrum of arsine was revisited in the region 4000–4350 cm-1 at a resolution of 0.006 cm-1. Altogether 189 energy levels of the local mode (110 A1/E) states were assigned by use of the ground state combination difference method. The vibration–rotation parameters were obtained from a weighted non-linear least-squares fit and discussed in the local mode model.\",\"PeriodicalId\":17286,\"journal\":{\"name\":\"Journal of the Chemical Society, Faraday Transactions\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1998-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Chemical Society, Faraday Transactions\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/A708723C\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Chemical Society, Faraday Transactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/A708723C","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
High resolution vibration–rotation spectra of the arsine local mode (110 A1/E) band
The high resolution Fourier transform spectrum of arsine was revisited in the region 4000–4350 cm-1 at a resolution of 0.006 cm-1. Altogether 189 energy levels of the local mode (110 A1/E) states were assigned by use of the ground state combination difference method. The vibration–rotation parameters were obtained from a weighted non-linear least-squares fit and discussed in the local mode model.
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