硫代联苯酰亚胺的合成及x射线结构测定

Sulfur Letters Pub Date : 2002-01-01 DOI:10.1080/02786110215844

M. Coogan, J. Platts, R. Haigh

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引用次数: 2

摘要

N, N -联苯酰亚胺的硫代化在寻找新的轴向手性配体中得到了低硫代联苯酰亚胺的混合物;x射线晶体学表明，二硫代二氧苯酞亚胺形成了非手性异构体1,3-二硫代氧- 1h - 3h -[2,2 ']生物异吲哚-1 '，3 ' -二酮，这可能表明单邻苯酞亚胺与二邻苯酞亚胺之间的硫化机理发生了变化。

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Synthesis and X-ray structure determination of thionated biphthalimides

Thiation of N , N -biphthalimide in a search for new axially chiral ligands gave a mixture of oligothiobiphthalimides; X-ray crystallography shows that the achiral isomer of dithiodioxobiphthalimide, 1,3-dithioxo-1H-3H-[2,2 ' ]biisoindolyl-1 ' ,3 ' -dione is formed, which may imply a change in the mechanism of thiation between mono- and di-phthalimides.

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Sulfur Letters

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