炭黑/木质素杂化对NR/BR复合材料流变学、力学和热稳定性的影响

IF 2.1 4区材料科学 Q3 MATERIALS SCIENCE, COMPOSITES

Plastics, Rubber and Composites Pub Date : 2021-09-27 DOI:10.1080/14658011.2021.1981718

N. M. Mohamad Aini, N. Othman, M. Hussin, K. Sahakaro, N. Hayeemasae

{"title":"炭黑/木质素杂化对NR/BR复合材料流变学、力学和热稳定性的影响","authors":"N. M. Mohamad Aini, N. Othman, M. Hussin, K. Sahakaro, N. Hayeemasae","doi":"10.1080/14658011.2021.1981718","DOIUrl":null,"url":null,"abstract":"ABSTRACT This study investigated the effect of hybrid carbon black/lignin on the rheological, mechanical and thermal stability of NR/BR composites. Three types of lignin, namely, Kraft lignin (KL), organosolv lignin (OL) and soda lignin (SL) were incorporated into rubber matrix at the filler loadings of 5–20 phr, where the total filler content was fixed at 50 phr. Based on the performance of the three types of lignin, the KL and OL-filled NR/BR composites showed better properties compared to SL-filled NR/BR composite. However, the inclusion of KL up to a loading of 10 phr in the rubber matrix showed comparable results with those of the NR/BR/CB50 (without lignin). It was observed that the minimum and maximum torque (ML and MH, respectively) of the composite with KL were improved. Furthermore, the incorporation of lignin in the NR/BR matrix reduced the Payne effect and enhanced their processability, thermal stability and aging resistance.","PeriodicalId":20245,"journal":{"name":"Plastics, Rubber and Composites","volume":"6 1","pages":"293 - 305"},"PeriodicalIF":2.1000,"publicationDate":"2021-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Effect of hybrid carbon black/lignin on rheological, mechanical and thermal stability properties of NR/BR composites\",\"authors\":\"N. M. Mohamad Aini, N. Othman, M. Hussin, K. Sahakaro, N. Hayeemasae\",\"doi\":\"10.1080/14658011.2021.1981718\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT This study investigated the effect of hybrid carbon black/lignin on the rheological, mechanical and thermal stability of NR/BR composites. Three types of lignin, namely, Kraft lignin (KL), organosolv lignin (OL) and soda lignin (SL) were incorporated into rubber matrix at the filler loadings of 5–20 phr, where the total filler content was fixed at 50 phr. Based on the performance of the three types of lignin, the KL and OL-filled NR/BR composites showed better properties compared to SL-filled NR/BR composite. However, the inclusion of KL up to a loading of 10 phr in the rubber matrix showed comparable results with those of the NR/BR/CB50 (without lignin). It was observed that the minimum and maximum torque (ML and MH, respectively) of the composite with KL were improved. Furthermore, the incorporation of lignin in the NR/BR matrix reduced the Payne effect and enhanced their processability, thermal stability and aging resistance.\",\"PeriodicalId\":20245,\"journal\":{\"name\":\"Plastics, Rubber and Composites\",\"volume\":\"6 1\",\"pages\":\"293 - 305\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2021-09-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Plastics, Rubber and Composites\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1080/14658011.2021.1981718\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Plastics, Rubber and Composites","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/14658011.2021.1981718","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}

引用次数: 3

摘要

研究了炭黑/木质素杂化对NR/BR复合材料流变、力学和热稳定性的影响。将硫酸盐木质素(KL)、有机溶剂型木质素(OL)和碱木质素(SL) 3种木质素添加到橡胶基体中，填料用量为5 ~ 20 phr，填料总含量固定为50 phr。综合三种木质素的性能，KL和ol填充的NR/BR复合材料性能优于sl填充的NR/BR复合材料。然而，在橡胶基体中掺入KL至10 phr的结果与NR/BR/CB50(不含木质素)相当。结果表明，加入KL后，复合材料的最小扭矩和最大扭矩(分别为ML和MH)均有所提高。此外，木质素在NR/BR基体中的掺入降低了Payne效应，提高了NR/BR的加工性、热稳定性和耐老化性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Effect of hybrid carbon black/lignin on rheological, mechanical and thermal stability properties of NR/BR composites

ABSTRACT This study investigated the effect of hybrid carbon black/lignin on the rheological, mechanical and thermal stability of NR/BR composites. Three types of lignin, namely, Kraft lignin (KL), organosolv lignin (OL) and soda lignin (SL) were incorporated into rubber matrix at the filler loadings of 5–20 phr, where the total filler content was fixed at 50 phr. Based on the performance of the three types of lignin, the KL and OL-filled NR/BR composites showed better properties compared to SL-filled NR/BR composite. However, the inclusion of KL up to a loading of 10 phr in the rubber matrix showed comparable results with those of the NR/BR/CB50 (without lignin). It was observed that the minimum and maximum torque (ML and MH, respectively) of the composite with KL were improved. Furthermore, the incorporation of lignin in the NR/BR matrix reduced the Payne effect and enhanced their processability, thermal stability and aging resistance.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Plastics, Rubber and Composites 工程技术-材料科学：复合

CiteScore

4.10

自引率

0.00%

发文量

审稿时长

4 months

期刊介绍： Plastics, Rubber and Composites: Macromolecular Engineering provides an international forum for the publication of original, peer-reviewed research on the macromolecular engineering of polymeric and related materials and polymer matrix composites. Modern polymer processing is increasingly focused on macromolecular engineering: the manipulation of structure at the molecular scale to control properties and fitness for purpose of the final component. Intimately linked to this are the objectives of predicting properties in the context of an optimised design and of establishing robust processing routes and process control systems allowing the desired properties to be achieved reliably.