Evaluating the Potential of Polylactide Nonwovens as Bio-Based Media for Air Filtration

The presented research aims to characterize hydrolytic resistance of highly crystalline and oriented polylactide (PLA) as a prerequisite for exploiting this bio-based material in durable applications. Industrially melt-spun PLA monofilaments and nonwovens have been subjected to environmental aging in a temperature range of 50–70 °C at a wide range of relative humidity (RH) in order to identify the onset of the material degradation under application conditions. Along with the measurements of mechanical and thermal behavior of the aged samples, the suitability of FTIR spectroscopy to probe the initial changes in the crystalline structure and in chemical composition of the fibers, caused by hydrolytic degradation, has been evaluated. The diagrams of stability and hydrolytic degradation under employed environmental aging for 7–14 days are presented for both types of PLA materials. Assessment of filtration performance of the artificially aged fibrous PLA media indicated a good agreement with the established stability diagram and confirmed the application potential of PLA nonwoven media, spun from currently available PLA grades, in air filtration under moderate climatic conditions up to max 50 °C and 50% RH. The presented results advance the knowledge on hydrolytic resistance of bio-based industry-relevant fibers and therefore open new application areas for sustainable materials with biodegradable components.